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WASTE DISCHARGE REQUIREMENTS ORDER NO. 5-00-031 -6- <br /> CITY OF LODI <br /> WHITE SLOUGH WATER POLLUTION CONTROL PLANT <br /> SAN JOAQUIN COUNTY <br /> from total to dissolved is CF=0.978 (for acute criteria) and CF=0.986 (for chronic criteria). <br /> 40CFR 122.45(c) requires that permit limits be expressed as total recoverable metal. A <br /> reasonable assumption is that the metal concentration in the receiving water is biologically <br /> available to the same extent as during the toxicity testing. Therefore, the water quality criteria, <br /> expressed as dissolved metal, has been divided by the EPA conversion factor, for the purpose of <br /> comparing the measured effluent concentrations with the criteria. Sampling results have shown <br /> that effluent concentrations of zinc have exceeded the converted acute and chronic criteria, and <br /> also the Basin Plan water quality objective if converted to total recoverable metal concentrations <br /> of 101 µg/l. The Basin Plan objective is the most stringent. The Board finds that zinc is or may <br /> be discharged ata level that will cause or have the reasonable potential to cause, or contribute <br /> to, an in-stream excursion above the Basin Plan water quality objective. An effluent limitation <br /> for zinc has been included in this Order based on the Basin Plan objective, with no mixing zone <br /> designated. The Discharger is not currently capable of meeting this limit. <br /> 25. Effluent monitoring for mercury has shown the median concentration to be non-detectable at <br /> <0.2 µg/1, and the highest measured to be 0.63 µg/1. The accuracy of the analyses is <br /> questionable without implementing `clean technique' for sample collection, handling. and <br /> analyses. The current EPA Ambient Water Quality Criteria for continuous concentration of <br /> mercury is 0.77 µg/1 (30-day average, chronic criteria), and the proposed California Toxics Rule <br /> concentration is 0.050 µg/1 (chronic criteria). The Sacramento-San Joaquin Delta has been <br /> listed as an impaired waterbody pursuant to Section 303(d) of the Clean Water Act because of <br /> mercury. This listing is based on elevated levels of mercury in fish tissue. Because the Delta <br /> has been listed as an impaired water body for mercury based on fish tissue impairment, the <br /> discharge must not cause or contribute to increased mercury levels in fish tissue. <br /> In view of the uncertainty of applicable water quality criteria and the accuracy of existing <br /> sampling results, this permit contains an interim performance-based effluent limit of_ <br /> 1.36 lbs/year for mercury. This interim mass limit was developed taking one-half of the average <br /> effluent mercury concentration (<0.2 µg/1) and applying that to the average daily flow of <br /> 5.6 mgd discharged to Dredger Cut for 8 months out of the year and including a ,20% allowance <br /> in mass loading to account for unforeseen variability in concentrations. The limit will not <br /> become effective until 1 January 2004, or one year after establishment and approval of a <br /> watershed mercury loading offset program. This Order requires monitoring for mercury using <br /> `clean technique', and allows the Board to reopen the permit to modify the interim effluent <br /> limits for mercury if it is determined to be necessary. In addition, the Discharger is required to <br /> develop a program for identification and control of mercury discharged within the collection <br /> system. <br /> 26. EPA's ambient water quality criteria for protection of aquatic life for a continuous concentration <br /> of lead is 3.7 µg/1 (30-day average, chronic criteria), based on a water hardness of 113 me, <br /> and as converted to be expressed as total recoverable metal. Effluent monitoring for lead has <br /> shown the median concentration to be 1.5 µg/1, and the highest measured to be 10 µg,n, with <br /> 3 of 18 samples exceeding the converted chronic criteria. Five of the 18 samples had a <br /> relatively high reporting/detection limit of 5.0 µg/l. The Board finds that lead is or may be <br />