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STIG PROJECT -- EVALUATION OF WATER FOR INJECTION -- 28 March 1994 <br /> Filtration <br /> Initial steps in preparing water for plant use involve removal of particulates. This is done <br /> in three stages. A multimedia filter removes the bulk of suspended particles, specifically those <br /> larger than about 20 microns (>0.0008 inches diameter). Backwash of this filter and subsequent <br /> filter pressing operations are forecast to produce about 25 pounds per day(10%moisture)of sludge <br /> for disposal. <br /> The water stream passing the multimedia filter is divided. Part goes to the cooling tower <br /> and receives a selection of conventional chemicals, but no additional processing. The other part <br /> passes through cartridge filters to remove particulates of 5 microns and larger (0.0002 inches). <br /> Cartridges are disposed of as solid waste. Fluids passing through the cartridge filters receive <br /> chemical additives. Chlorination aims to prevent bacterial growth. Dispersants aim to keep <br /> suspended particles suspended so they may be carried away in the liquid stream instead of fouling <br /> subsequent units. <br /> Chemically modified fluid enters the ultrafilter which removes particulates as small as 0.1 <br /> micron(0.000004 inches).This step is helpful for reducing fouling of the RO unit. Ultrafiltration <br /> also causes a mild separation of dissolved materials. Permeate (product) passing the ultrafilter is <br /> reduced in dissolved components by a factor(multiplier)in the range of 0.91 to 0.93. The effluent <br /> (waste) discharge is more concentrated in dissolved materials by a factor of 1.2 to 1.4, relative to <br /> the input concentration. The numerical values of these concentration multipliers vary modestly <br /> with the ratio of product to waste and with the condition (age) of the filter material. This stream <br /> also carries particulates and enters the waste receiver tank where it is the least concentrated of the <br /> three major streams mixed there. It may be regarded as providing a mild dilution effect. Product <br /> from the ultrafilter goes to the reverse osmosis (RO) unit. <br /> Reverse Osmosis <br /> Molecular size holes in the RO membrane enable a separation in which about three fourths <br /> of the input water passes through the membrane, becoming product, while carrying only five to <br /> ten percent of initial amount(by weight)of dissolved salts. Effluent from the RO unit at STIG will <br /> be more concentrated than the input by factors near 2.9. This stream carries the largest single <br /> contribution of dissolved components to the mixture intended for injection/disposal, but is <br /> volumetrically smaller than the ultrafilter waste during normal operations. <br /> A variety of additives are used to control chemical deposition on the membranes where <br /> concentrations can be locally high.Internal concentration multipliers exceed 2.9,which represents <br /> an average related to gradients near the membrane. Some added chemicals are intended for this <br /> environment, to suppress deposition on and in the membrane. Selection of additives depends on <br /> the composition of input liquid and the concentration factor involved with the separation effects. <br /> Control of pH is important and usually involves reducing natural alkalinity by adding a small <br /> stream of sulfuric acid. <br /> Silica in the WSWCPF source water is the component which limits the concentration effect <br /> that is practical in the RO unit at STIG. Normal operation at STIG results in those silica <br /> concentrations reaching, and sometimes exceeding, concentrations which could yield silica scales. <br /> Such deposition could plug the RO membrane.Careful and continued avoidance of plugging is one <br /> essential part of the proposed operations, which involves added chemical dispersants. <br /> DON MICHELS ASSOCIATES -Missoula,Montana USA <br />