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I <br /> i. <br /> 2.2.1 SVCA Sam lin <br /> i <br /> Before each sample was collected, a vacuum pump was used to purge <br /> Previously collected vapor from the probe to ensure that the <br /> sample was not contaminated. The vactxum pressure reading on the <br /> Purging apparatus was recorded. This vacuum <br /> -. pressure is related <br /> to the soil's gas permeability and is useful in data interpreta- <br /> tion. High vacuum readings suggest g g that there is a resistance to - <br /> soil gas movement and a vacuum is being created between the tip <br /> ;f of the probe and the um ? <br /> 3 pump. f this vacuum is maintained through <br /> the pumping period a representative sample of the soil <br /> s <br /> not be obtained, and anomalously low hydrocarbon readings may <br /> result. In most situations, initial vacuums are released and the <br /> i vacuum pressure readings drop. A low reading indicates that <br /> i there is a free flow of soil <br /> gas from the vadose zone through the <br /> "�- probe, and after purging the sample is assumed to be <br /> i s <br /> - representative. <br /> In addition to obtainingsoil <br /> gas samples, if there were <br /> monitoring wells on the site; well headspace samples were .also <br /> :- <br /> } analyzed for hydrocarbon contents. Before a sample was taken, <br /> the well was capped with a rubber stopper to <br /> prevent atmospheric s <br /> air from entering it. A vacuum pump was used to purge the well ' <br /> ' and draw soilz <br /> gas through the screened sections of the well <br /> casing.. Again,` anomalously low results may be obtained if the - <br /> 6 <br /> J well is improperly screened (e.g., the to of <br /> p the well screen ng <br /> is below the top of the water:table) , because soil gas will not <br /> be properly transported. <br /> J <br /> The soil vapor and monitoring well headspace samples were <br /> y <br /> collected through a septum with a microsyringe and in 'erted ' <br /> the gas chromatograph. A Photovac 10850 gas chromatograph was <br /> to <br /> ' used. for the 23 and 24 November survey: an HNu 421 for the <br /> shallow survey performed on 22 December. <br /> s EXXON9:84I; 8 <br /> + t s <br />