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k4 KLEINF>ELDER <br /> 4 ACTIVITIES CONDUCTED <br /> Kleinfelder conducted the groundwater sampling for the Third Quarter 2005 <br /> groundwater monitoring. Kleinfelder measured water levels in all but one (MW-4, <br /> obstructed) of the monitoring wells and piezometers, and sampled 13 monitoring wells <br /> and piezometers (MW-DIS-1, MW-DIS-2, MW-DIS-9, MW-DIS-11s, MW-DIS-11d, MW- <br /> DIS- 12, MW-DIS-13, MW-DIS-14s, MW-DIS-14d, MW-DIS-15, NP1-70, NP1-80, and <br /> NP1-90). The wells and piezometers were previously surveyed by Kjeldson, Sinnock, <br /> Neudeck, Inc. (KSN, Inc.) of Stockton, California on February 14, 2002 so groundwater <br /> gradients could be calculated. Measurements obtained from the wells were used to <br /> evaluate groundwater gradient, groundwater impacts and the need for additional <br /> assessment. Photo-ionization detector (PID) samples were collected from vapor <br /> extraction wells (VE-1, VE-2, VE-3, VE-4, VE-5, and mainline). Air inlet and outlet <br /> samples were also collected from the thermolcatalytic oxidizer. Also during the quarter, <br /> DWR Well Drillers Logs were reviewed from within a 2,000-foot radius of the site to <br /> evaluate possible groundwater flow influences. <br /> 4.1 MEASUREMENT OF WATER LEVELS <br /> To assess the groundwater gradient at the time of sampling, water level measurements <br /> were made in each of the nineteen (excluding MW-4) monitoring wells and three <br /> piezometers at the beginning of the sampling round, prior to purging and sampling of <br /> the wells. The depth-to-water was measured in each well according to the protocol <br /> described in Appendix A, Section A-4.1. The depth-to-water measurements were then <br /> converted to relative groundwater elevations with respect to a surveyed benchmark by <br /> subtracting them from the surveyed casing elevations. August 29, 2005 depth to water <br /> measurements are included in the Record of Water Level Measurements in Appendix <br /> B. The Monitoring Well Construction Detail can be found in Table 1. <br /> The resulting groundwater elevations were used to assess the direction of the <br /> groundwater gradient at the time of sampling. This information was then used to <br /> assess which wells represent upgradient and downgradient groundwater conditions. <br /> See Table 2 for the groundwater elevation data. <br /> Plate 2 shows the location of the groundwater monitoring wells. The depth to <br /> groundwater ranged from 44.46 feet below the top of the well casing (MW-DIS-11 s) to <br /> 53.67 feet below the top of the well casing (MW-DES-14d). Groundwater elevations for <br /> the monitoring wells ranged from —33.56 feet MSL (MW-DIS-6) to -34.12 feet MSL <br /> (MW-DIS-13). A groundwater gradient direction was estimated based on depth-to- <br /> water data collected from the wells. The groundwater gradient was relatively flat on <br /> h August 29, 2005 towards the east/southeast at 0.0004 ft./ft. A groundwater elevation <br /> contour map is included as Plate 3. In areas of relatively flat groundwater gradients <br /> such as this site, groundwater gradients may significantly fluctuate due to rainfall, <br /> groundwater recharge, groundwater pumping, etc. Therefore, changes in groundwater <br /> 12280.M0NIST05R14241CD:Iv Page 7 of 14 <br /> 0 2005, Kleinfelder, Inc. November 15,2005 <br />