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Ms. Shelby Lathrop -2 - 31 December 2008 r <br /> Former Tosco Bulk Terminal No. 10013 <br /> well MW-20 and to convert monitoring well MW-22C into an injection point using downhole <br /> inflatable packers. <br /> Oxygen injection events are scheduled to be completed twice a month by injecting 300 ft3 of <br /> bottled oxygen per event over a two-day period in each of the nine injection points. DO <br /> concentration monitoring will be conducted in 12 monitoring wells, including eight A zone wells <br /> (MW-2, MW-8, MW-14, MW-16, MW-20, and P-1 through P-3), three B zone wells (MW-17B, <br /> P-4, and P-5) and one C zone well (MW-19C) prior to and immediately following each injection <br /> event. The Work Plan does not propose petroleum hydrocarbon monitoring specifically for the <br /> oxygen injections. <br /> ConocoPhillips conducts groundwater monitoring at the Site pursuant to Monitoring and <br /> Reporting Program (MRP) No. R5-2004-0824. The 30 October 2008 Quarterly Status Summary <br /> Report, Third Quarter 2008 describes groundwater monitoring activities performed in August <br /> 2008. The groundwater flow directions in the A, B, and C zones were to the southwest. The <br /> gradients ranged from 0.001 feet per foot (ft/ft) in the C zone to 0.004 ft/ft in the A zone. <br /> During the second quarter, TPHg was non-detect (ND) in all but one well, MW-3, which <br /> contained 96 micrograms per liter (pg/L) of TPHg. The highest concentration of TPHd was in <br /> MW-17B at 190 pg/L. MW-2 contained the highest concentration of TBA at 420 pg/L, and MW- <br /> 17B had the highest concentration of MTBE at 18 pg/L. <br /> Our comments are presented below. <br /> 1. The Work Plan does not propose a specific length of time over which this phase of the pilot <br /> study will be performed or whether DO injection has been selected as the groundwater <br /> remedy for this Site. If the proposed work is a continuation of the pilot study that began in <br /> December 2007, a termination date has to be established. If ConocoPhillips has selected <br /> oxygen injection as a the groundwater remedy for this site, then the technology must be <br /> clearly identified as such in a Remedial Action Plan, so that the Regional Water Board can <br /> provide concurrence, if appropriate. <br /> 2. The A and B zone injection points that the Work Plan recommends installing near MW-20 <br /> are positioned cross-gradient of this monitoring well. It seems that, an upgradient position <br /> would be more advantageous for optimizing the delivery of oxygen to this well. <br /> ConocoPhillips needs to provide the rationale behind selecting the cross-gradient location <br /> for these injection points. <br /> 3. During pilot testing, monitoring results obtained from MW-17B showed that DO levels did not <br /> increase, DIPE and TBA concentrations increased slightly, and TPHd levels were ND. Third <br /> quarter monitoring results, however, show that the TPHd concentration in this well increased <br /> to 190 pg/L. In the 25 July 2008 Oxygen Injection Pilot Study Report (Report), <br /> ConocoPhillips recommended installing an oxygen injection well in the vicinity of MW-17B to <br /> address the deficient DO and elevated DIPE and TBA concentrations. However, that <br /> recommendation is absent from the Work Plan. ConocoPhillips needs to explain why an <br /> injection point in the vicinity of MW-17B is no longer being considered. <br />