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Stericycle' • Environmental Solutions (4)Concentration of diluents. I he fourth column specifies the type and concentration(mass percent)of diluent or inert solid,when required.Uther types and concentrations of diluents may be used if approved by the Associate Administrator. (i)The required mass percent of"Diluent type A"is specified in column 4a.A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150'C at atmospheric pressure.Type A diluents may be used for desensitizing all organic peroxides. (ii)The required mass percent of"Diluent type B"is specified in column 4b.A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point,at atmospheric pressure,of less than 150°C(302°F)but at least 60'C(140°F),and a flash point greater than 5'C(41°F).Type B diluents may be used for desensitizing all organic peroxides,when specified in the organic peroxide tables,provided that the boiling point is at least 60'C(140°F)above the SADT of the peroxide in a 50 kg(110 lbs)package.A type A diluent may be used to replace a type B diluent in equal concentration. (iii)The required mass percent of"Inert solid"is specified in column 4c.An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic (5)Concentration of water. Column 5 specifies,in mass percent,the minimum amount of water,if any,which must be in formulation. (8)Notes.Column 8 specifies other applicable provisions. 1.For domestic shipments,OP8 is authorized. 2.Available oxygen must be<4.7%. 3.For concentrations<80%OPS is allowed.For concentrations of at least 80%but<85%,OP4 is allowed.For concentrations of at least 85%,maximum package size is OP2. 4.The diluent may be replaced by di-tert-butyl peroxide. 5.Available oxygen must be 59%with or without water. 6.For domestic shipments,OP5 is authorized. 7.Available oxygen must be 558.2%with or without water. 8.Only non-metallic packagings are authorized. 9.For domestic shipments this material maybe transported under the provisions of paragraph(h)(3)(xii)of this section. 10.[Reserved] 11.[Reserved] 12.Samples may only be offered for transportation under the provisions of paragraph(b)(2)of this section. 13."Corrosive"subsidiary risk label is required. 14.[Reserved] 15.No"Corrosive"subsidiary risk label is required for concentrations below 80%. 16.With<6%di-tert-butyl peroxide. 17.With 58%1-isopropylhydroperoxy-4-isopropylhydroxybenzene. 18.Addition of water to this organic peroxide will decrease its thermal stability. 19.[Reserved] 20.Mixtures with hydrogen peroxide,water and acid(s). 21.With diluent type A,with or without water. 22.With 2:36%diluent type A by mass,and in addition ethylbenzene. 23.With 2:19%diluent type A by mass,and in addition methyl isobutyl ketone. 24.Diluent type B with boiling point>100 C. 25.No"Corrosive'subsidiary risk label is required for concentrations below 56%. 26.Available oxygen must be 57.6%. 27.Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41%with water,total active oxygen less than or equal to 9.5%(peroxyacetic 28.For the purposes of this section,the names'peroxyacetic acid"and"Peracetic acid"are synonymous. 29.Not subject to the requirements of this subchapter for Division 5.2. 30.Diluent type B with boiling point>130°C(266°F). 31.Available oxygen 56.7%. TYPE IDEFINITION A An organic peroxide which can detonate or deflagate rapidly as packaged for transport. Transportation of a type A organic peroxide is forbidden B An organic peroxide which,as packaged for transport,neither detonates nor deflagates rapidly,but can undergo a thermal explosion C An organic peroxide which,as packaged for transport,neither detonates nor deflagates rapidly,and can not undergo a thermal explosion An organic peroxide which;(i)detonates only partially,but does not deflagate rapidly and is not affected by heat when confined D (ii)does not detonate,deflagate slowly,and shows no violent affect if heated when confined;or iii does not detonate,defla ate slowly,and shows a medium affect when heated under confinement E An organic peroxide which neither detonates nor deflagates and shows low,or no,affect when heated under confinement. F An organic peroxide which will not detonate in a captivated state,does not deflagate,shows only a low,or no,affect when heated under confinement,and has a low,or no,explosive power G An organic peroxide which will not detonate in a captivated state,will not deflagate at all,shows no affect when heated under confinement,and shows no explosive power MAXIMUM QUANTITY OF PACKAGING PER PACKAGE FOR ORGANIC PEROXIDES OP3=SOLID WASTE.5 KILOGRAMS PER INNER CONTAINER;LIQUID WASTE;.5 LITER PER INNER CONTAINER OP2=SOLID WASTE.5 KILOGRAM PER INNER CONTAINER,10 KILOGRAM MAX PER OUTER CONTAINER;LIQUID WASTE; SAME OP3=SOLID WASTE;5 KILOGRAMS PER INNER CONTAINER;LIQUID WASTE; SAME OP4=SOLID WASTE;5 KILOGRAMS PER INNER CONATINER,25 KILOGRAMS PER OUTER CONTAINER;LIQUID WASTE; SAME OPS=SOLID WASTE;25 KILOGRAMS PER INNER CONTAINER;LIQUID WASTE; SAME OP6=SOLID WASTE;50 KILOGRAMS PER INNER CONTAINER;LIQUID WASTE;60 KILOGRAMS PER INNER CONTAINER OP7=SOLID WASTE;50 KILOGRAMS PER INNER CONTAINER; LIQUID WASTE;60 KILOGRAMS PER INNER CONTAINER OPS=SOLID WASTE;400 KILOGRAMS PER INNER CONTAINER; LIQUID WASTE;225 KILOGRAMS PER INNER CONTAINER Maximum Quantity Per Packaging/Package [For Packing Methods OP1 to OP8] ©Stericycle 2015.All rights reserved. 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