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■ Stellriccle` # Envimnmental Solutioms DOT Class 4Metal Powders & Compounds DWW INC15-W 4.3 Flammable Solids Dangerous When Wet Q 1 The compounds in this category react violently with water and emit a flammable or toxic or corrosive gas. 2 Incinerators have metal feed limits. Reference the metal feed limits before packing. 3 Water reactive metal powders should be submerged in oil,but not required. 4 Water-reactive amides are a Group A severe peroxide former.Evaluation is required. HANDLE WITH EXTREME CAUTION,reference peroxide former tab. 1 Package Rating: PG II(Y-rated),PG I (X-rated)for Phosphides(6.1 PGI)and Zinc*and Mg (sub 4.2 PG I) 2 Maximum inner container size: 25 lbs.(Sub 4.2 are limited to 4.4 lbs.) 3 Maximum outer container size: 15 gallon 4 Maximum package weight: 40 lbs.(sub 4.2 are limited to 22 lbs.of self-heating material) notes: *Reference metal feed limits for exceptions. Placarding for Dangerous When Wet required with any quantity,unless packaged in a Spec Box(Special Exemption Box). Use the Spec Box if travelling on restricted routes,such as tunnels. ***All phosphides are packed alone due to Sub 6.1 PG I toxicity. Process code: INC15-W Think! -(boro)hydride, Provisions: Pack separate from alkali metals&4.3 solvents -carbide, -phosphide, -amide RCRA codes D001 D003 DOT n.o.s. UN3132,UN3208 (metal powders) examples: Water-reactive solid (UN2813) n.o.s. Water-reactive Solid.flammable(UN3132)n.o.s. Borohydrides(Li,K,Na,NaAI,exceptAl(4.2)and many organo) Phosphorous pentasulfide(U189) (UN1340) Carbides (Aluminum (UN1394)and Calcium(UN 1402)) Hydrides(Al,Ca,Li,LiAI,Mg,except many organo) Metallic substance,water-reactive.self-heating Silicide(Calcium(UN1405)and Magnesium (UN2624)) 4.3(4.2) (UN3209)n.o.s.(container limits above), Lithium Nitride(UN2806) Magnesium powder(UN1418) Maneb stabilized(U114) (UN2968)PG III Zinc powder(UN1436) Potassium amide***(UN1390) Metal Powders(UN3208)n.o.s. Sodium amide*** (UN1390) Aluminum powder,uncoated[dull in appearance](UN1396) Water-reactive Solid.Toxic(UN3134)n.o.s. Aluminum Silicon powder,uncoated (UN1389) Aluminum ferrosilicon,powder(UN1395) Barium powder(UN1400) Ferrosilicon,powder(UN1408) Calcium(UN1401) Phosphides*(Al,Ca,MgAI,Mg,K,Na,Sn,Sr,and Zn) Cerium,turnings (UN3078) Sodium cyanoborohydride**(PGII-reactive cyanide) Magnesium granules,coated(UN2950) Zinc ashes (UN1435) *All phosphides are packed alone due to Sub 6.1 PG I toxicity in x-rated containers. **Pack sodium cyanoborohydride to cyanide packaging and segregation requirements. ***Sodium amide and Potassium amide are severe peroxide formers,evaluation is required prior to packing. Inglewood cannot accept D003 wastes. PACKING ENVELOPE NOMENCLATURE: INC15-W solids © Stericycle 2015.All rights reserved. Confidential Information: Copying, dissemination or distribution of this information is strictly prohibited.