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V - INFORMATION SHEET ORDER NO, R5-2008-0149 1 IN-SITU GROUNDWATER REMEDIATION AT SITES WITH VOLATILE ORGANIC COMPOUNDS, NITROGEN COMPOUNDS, PERCHLORATE, PESTICIDES, ' `I SEMI-VOLATILE COMPOUNDS AND/OR PETROLEUM HYDROCARBONS Volatile organic compunds (VOCs), petroleum hydrocarbons, perchlorate and fumigants have impacted groundwater at numerous sites within the Central Valley Region and cause or threaten adverse impacts to existing and potential beneficial uses of groundwater resources. Those sites are being required to clean up the pollution and restore the beneficial uses of the groundwater. This cleanup can take many forms. The two most common methods of cleanup of groundwater pollution are pump and treat, and in-situ remediation. The operation and discharge of a pump and treat system is generally regulated under site- specific or general waste discharge requirements. Prior to this General Order, in- situ groundwater remediation projects have had site-specific waste discharge requirements issued. The process to develop and adopt site-specific waste discharge requirements can be lengthy. Many in-situ treatment processes have common components and issues that can be regulated under general waste discharge requirements. In-situ remediation of groundwater pollution at most sites includes the use and application of biological, chemical, and/or physical treatment processes. These processes include addition of oxygen , chemical oxidation/reduction , and the addition of nutrients, carbon and/or bacteria to enhance biodegradation. The method of delivery can be via injection to soil or groundwater insitu, or via groundwater recirculation (extraction and treatment with return of treated groundwater to the impacted aquifer zone) . In most instances the in-situ remediation processes will cause reducing or oxidizing conditions within the aquifer in order to either reduce or oxidize the target pollutant. The remediation processes can result in exceedances of water quality objectives that are generally limited in duration and/or in a relatively small portion of the aquifer. hese-waste-discharge-requirerrrents-allow-exceedance7a-of-watergaali objectives to occur while oxidation/reduction processes are taking place, but only within the treatment zone. Oxidation/reduction reactions take place when an electron is transferred from one compound to another. The electron donor becomes oxidized , and the electron receptor becomes reduced. These are always coupled reactions. If a compound is reduced, another must necessarily be oxidized to provide the electron . Reducing environments are typified by the absence of oxygen and are also referred to as anaerobic environments. Oxidative environments contain oxygen and are also referred to as aerobic environments. Reducing Environment Processes The primary reduction processes that are effective on perchlorate and VOCs are anaerobic in nature as aerobic processes are generally not effective on most highly chlorinated VOCs. Aerobic dechlorination or aerobic cometabolism of perchloroethylene (PCE) and trichloroethylene (TCE) has not been successful at