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CLEARWATER GROUP Groundwater Monitoring and Sampling Field Procedures Groundwater Monitorin Pnor to beginning, a decontamination area is established Decontamiriah on procedures consist of scrubbing downhole equipment in an Alconox® solution wash(wash solution is pumped through any purging pumps used), and rinsing in a first rj=of potable water and a second rinse of potable water or demonized water if the latter is required Any non-dedicated downhole equipment is decontaminated prior to use Prior to purging and sampling a well, the static water level rs measured to the nearest 0 Ol feet with an electronic water sounder Depth to bottom is typically measured once per year, at the request of the project manager, and during Clearwatees first visit to a site If historical analytical data are not available, with which to establish a reliable order of increasing well contamination,the water sounder and tape will be decontaminated between each well If floating separate-pbase hydrocarbons (SPH) are suspected or observed, SPH is collected using a clear, open-ended product bailer, and the thidmess is measured to the nearest 0 01 feet in the bailer SPH may alternatively be measured with an electronic interface probe Any monitoring well containing a measurable thickness of SPH before or during purging its not additionally purged and no sample rs collected from that well Wells containing hydrocarbon sheen are sampled unless otherwise specified by the project manager Field observations such as well integrity as well as water level measiuements and floating product thicknesses are noted on the Gauging Datall i rge Calculations form well Purg,n Each monitoring well to be sampled is purged using either a PVC bailer or a submemsrble pump Physical parameters(pH,temperature and conductivity)of the purge water are monitored during purging activities to assess if the water sample collected is representative of the aquifer If required, parameters such as dissolved oxygen, turbidity, salinity etc are also measured. Samples are considered representative if parameter stability is achieved Stability is defined as a change of less than 0 25 pH units, less than 10%change in conductivity in micro mhos, and less than 10 degree centigrade(1 8 degrees Fahrenheit)change in temperature Parameters are measured in a discreet sample decanted from the bailer separately from the rest of the purge water Parameters are measured at least four times during purging; initially, and at volume intervals of one well volume Purging continues until three well casing volumes have been removed or until the well completely dewaters Wells which dewater or demonstrate a slow recharge may be sampled after fewer than three well volumes have been removed Well purging information is recorded on the Purge Data sheet_ All meters used to measure parameters are calibrated daily Purge water is sealed, labeled, and stored on site in D O T approved 55-gallon drums After being chemically profiled,the water is removed to an appropriate disposal facility by a licensed waste hauler Groundwater Sample Collection Groundwater samples are collected immediately after purging or, if purging rate exceeds well recharge rate,when the well has recharged to at least 811%of its static water level If recharge rs extremely slow,the well is allowed to recharge for at least two hours, if practicable, or until sufficient volume has accumulated for sampling The well is sampled within 24 hours of purging or repurgcd Samples are collected using polyethylene bailers, either disposable or dedicated to the well Samples being analyzed for compounds most sensitive to volatilization are collected first Water samples are placed in appropriate laboratory-supplied containers, labeled, documented on a chain of custody form and placed on ice in a cooler for transport to a state-certified analytical laboratory Analytical detection hurts match or surpass standards required by relevant local or regional guidelines QjWq Assurance Procedures procedures in the field To prevent contamination of the samples,Clearwater personnel adhere to the following p • A new,clean pair of latex gloves is put on pnar to sampling each well . Wells are gauged,purged and groundwater samples are collected nn the expected order of increasing degree of contamination based on historical analytical results CLEARWATER GROUP(GWS) l revised Apnl 4,2002