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GEOMATRIX <br /> Mr. Don O. Culbertson <br /> Chevron Pipe Line Company <br /> 8 March 1995 <br /> Page 7 <br /> and TRPH at wells MW-13, MW-23, MW-24, which are screened across crude oil- <br /> affected soil, and MW-22 during the next quarterly monitoring event to evaluate the <br /> success of this technique in removing the non-dissolved fraction. Further, we will <br /> instruct the laboratory to perform a silica gel cleanup on the filtered samples to be <br /> analyzed for TPH to mitigate the effects of soluble non-PHCs influencing the <br /> Method 8015 result. Silica gel cleanup is required for Method 418.1. Samples <br /> collected for BTEX and PNA analyses will not be field-filtered or subject to silica <br /> gel cleanup. <br /> If BTEX and PNAs are non-detect and TPH or TRPH (filtered) shows detections, <br /> this would suggest that 1) the field filtration is not capable of removing all of the <br /> non-dissolved portion and/or 2) the sample contains soluble non-PHCs (biogenic <br /> materials) that are being measured by the TPH or TRPH analysis and are not being <br /> removed by the silica gel cleanup. We will review the chromatograms to evaluate <br /> the cause for the TPH detections. Detections of TRPH will be further analyzed by <br /> GC/MS on selected TRPH extract(s) to identify soluble non-PHCs such as microbial <br /> lipids or fatty acids. We believe, based on the discussion presented herein, that <br /> results from such analyses will provide a more accurate assessment of dissolved- <br /> phase PHC concentrations and the potential for transport of PHCs in groundwater at <br /> the site. <br /> Please call me at any time to discuss this information. We look forward to your response <br /> and the application of this approach at the Dividend property. <br /> Sincerely, <br /> GEOMATRIX CONSULTANTS, INC. <br /> Dawn A. Zeo, C.E.G <br /> Senior Hydr6geolegist <br /> DAZ\lam <br /> CONT\C2677TPH.LTR <br /> Attachments: References <br /> Table 1 - <br /> Figures <br /> cc: Karen Svnowiec - Chevron Research and Technology Company <br />