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GEOMATRIX <br /> Ms. Wendy Cohen <br /> Regional Water Quality Control Board - Central Valley <br /> 7 November 1994 <br /> Page 3 <br /> data provided on the large site plan submitted to RWQCB on 13 October 1994 showed that <br /> the lateral and vertical extent of petroleum-affected soil has been defined. <br /> Mr. Moody also commented that the soil samples should be screened using a photoionization <br /> detector (PID) to detect benzene, toluene, ethylbenzene, or xylenes (BTEX). Our workplan <br /> states that we will use field vapor readings to assist us in determining which samples should <br /> be sent to the laboratory for analysis (p. S, first paragraph). Field vapor readings will be <br /> obtained using a PID; each soil boring will be screened with a PID to determine stratigraphic <br /> intervals with high vapor readings. Soil samples from intervals with the highest PID <br /> readings in each boring will be sent to the laboratory for analysis. <br /> WATER QUALITY EVALUATION <br /> Mr. Moody's letter requested that a "water quality model" be developed for the site to <br /> identify the potential for hydrocarbons in the soil to migrate into the groundwater if the soil <br /> is left in place. Our submittal of 13 October 1994 provided the locations and analytical <br /> results of all soil and groundwater samples collected to date for the project. As shown on <br /> the site plan, petroleum-affected soil occurs at a depth that includes the capillary fringe and <br /> the saturated zone. We also understand that the petroleum may have been in the subsurface <br /> for at least 50 years, because the pipeline was removed from service in the mid-1940s. <br /> Consequently, the project groundwater data can be approached as results of an in-situ <br /> leaching test. <br /> Accordingly, our strategic model for the site is built on this conceptual foundation and we <br /> use the data from the site as real-time evidence of what is happening in the subsurface. The <br /> physical distribution of chemical analytical data at the site makes mathematical/chemical <br /> modeling or the extrapolation of laboratory leaching tests unnecessary. Real-time site data <br /> from the first quarterly sampling event in 1994 show that the petroleum in the saturated or <br /> unsaturated subsurface is not providing a source of dissolved petroleum constituents to <br /> groundwater. This conclusion will be confirmed via the quarterly monitoring program. As <br /> you know, the soluble constituents in petroleum weather very rapidly due to their chemical <br /> structure. Therefore, if the material is not very soluble today, it will be even less soluble in <br /> the future. <br /> We trust that this response adequately addresses the comments in Mr. Moody's letter. We <br /> have received agreement from DTSC for review of the SHRA work plan, therefore we <br /> request your approval of the stockpiled and drummed soil sampling proposal in this letter by <br />