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GROUNDWATER TECHNOLOGY, INC. <br /> STANDARD OPERATING PROCEDURE <br /> CONCERNING WATER SAMPLING METHODOLOGY <br /> SOP 0 <br /> Before water sampling, each well shall be purged by pumping a minimum of four well volumes or until the <br /> discharge water Indicates stabilization of temperature conductivity and pH. if the well Is evacuated before <br /> four well volumes are removed or stabilization is achieved,the sample should be taken when the water level <br /> in the well recovers to 80 percent of its initial level. <br /> Retrieval of the water sample, sample handling and sample preservation shall be conducted according to <br /> Standard Operating Procedure 10 concerning "Sampling for Volatiles In Water." The sampling equipment <br /> used shall consist of a Teflon® and/or stainless steel samplers which meet U.S. Environmental Protection <br /> Agency (EPA) regulations. Glass vials with Teflon® lids should be used to store the collected samples. <br /> To ensure sample integrity, each vial shall be filled with the sampled water In such a way that the water <br /> stands above the lip of the vial. The cap should then be quickly placed on the vial and tightened securely. <br /> The vial should then be checked to ensure that air bubbles are not present prior to labeling of the sample. <br /> Label Information should include a sample identification number, job identification, date, time, type of <br /> analysis requested, and sampler's name. Chain-of-custody records shall be completed according to <br /> Standard Operating Procedure (SOP) 11 concerning chain of custody. <br /> The vials should be Immediately placed in high quality coolers for shipment to the laboratory. The coolers <br /> should be packed with sufficient Ice or freezer packs to ensure that the samples are kept below 4°Celsius <br /> (C). To minimize sample degradation the prescribed analysis shall take place within seven days of sample <br /> collection unless specially prepared acidified vials are used. <br /> To minimize the potential for cross contamination between wells, all the well development and water <br /> sampling equipment which contacts the groundwater shall be cleaned between each sampling. As a second <br /> precautionary measure, the wells shall be sampled in order of Increasing contaminant concentrations (the <br /> least contaminated well first, the most contaminated well last) as established by previous analysis. <br /> OW,GROUNDWATER <br /> 0 TECHNOLOGY,INC, <br />