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Workplan for Vertical Groundwater Investigation <br /> And Bench Test for In-Situ Oxidation <br /> 7835 Thornton Road, Stockton, CA <br /> Page 3 of 8 <br /> feet bgs. Groundwater has been as high as 29.5-31.5 feet bgs in May 2000. Groundwater beneath <br /> the site generally flows to the east with an average gradient ranging of approximately 12 to 20 feet <br /> per mile. The groundwater gradient calculated from data collected in November 2005 is depicted <br /> on Figure 8. <br /> Residual Hydrocarbons in Soil <br /> Analytical results of soil samples collected during subsurface investigations to date indicated <br /> gasoline hydrocarbon impacted soil was initially present in the vicinity of the former underground <br /> fuel storage tanks and fuel dispensers from approximately five feet below grade to the water table <br /> (at least 55 feet below grade). Subsequent excavation activities removed impacted soils to a depth <br /> of approximately 35 to 40 feet below grade, the maximum practical depth for excavation. <br /> Laboratory analyses of confirmation soil samples collected from the excavation indicated that soil <br /> contaminants were removed laterally, but impacted soils remained in the interval from <br /> approximately 35 feet bgs to at least 45 feet bgs in borings SB 1, SB 12, and SB 14 and to 50 feet bgs <br /> in boring MW5. The analytical results of soil samples collected during drilling of the deep borings <br /> in 1998 suggest that very low levels of gasoline constituents may persist to a depth of at least 98 <br /> feet bgs. Soil contamination appeared to attenuate significantly with depth, however, as the highest <br /> hydrocarbon concentrations in the soil were detected between 35 and 55 feet bgs, which <br /> corresponds to the zone of historic groundwater fluctuation and consists predominantly of fine- <br /> grained soils such as clays with some silts and clayey sand. <br /> An estimated 1,600 pounds of residual gasoline remains in saturated soil, approximately 1,500 <br /> pounds of which resides between the depths of approximately 35 and 55 feet. Attachment 2 <br /> contains a table summarizing calculations for residual gasoline remaining in soil. <br /> Dissolved Hydrocarbons in Groundwater <br /> Subjective analyses of groundwater in site monitoring wells indicated that no wells exhibited any <br /> free-floating hydrocarbons since December 1990 (well MW5), but petroleum product sheen was <br /> noted in December 1993. Analytical results of groundwater samples collected from site wells in <br /> 2005 indicate that TPHg and benzene is present in two site wells. Consistently low levels of <br /> dissolved hydrocarbon constituents have been detected in well MW1, located at the edge of the <br /> plume. Elevated levels of dissolved hydrocarbon constituents persist in well MW5, located <br /> approximately 30 northeast of the location of the nearest former product dispenser. Historical <br /> groundwater analytical results are presented in Attachment 1. <br /> Based upon the extent of dissolved petroleum hydrocarbons in groundwater beneath the site <br /> (November 2005) and assuming a soil porosity of 25% within the saturated zone (35-55 feet bgs), <br /> the mass of dissolved gasoline in groundwater beneath the site was calculated to be approximately <br /> 22 pounds. Attachment 2 contains a table summarizing calculations for residual gasoline remaining <br /> in groundwater. <br /> G:\GROLTNDZE\KNOWLES.HAM\REPORTS\WKPLAN—deepwell_bench2.doc <br />