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GPGenium Publishing Corporation Material Safety Data Sheea Collection:
<br /> 1145 Catalyn Strut. Sheet No.467 `
<br /> Schenectady,Ny 12303-1836 USA Automotive Gasoline,Lead-free
<br /> (518)377-8854
<br /> >;aecflolz . NXatezlal`Iient Issued 10/81 Revision:
<br /> jj
<br /> Automotive free
<br /> Gasollnq Lead 1f c8t1pi1« : . a� xr� h j •> xf.,.,' .yv :.:y .. >K ...>::r'.i.:. A'9/91
<br /> ,Descrlptton:A mixture; volat7e h "'"" M `
<br /> Paraffiat,rycloparaT=,okfins,naphdmes,and arornatia.In ever y`�Oeirb°K composed mainly of bramcheds ha;m R 1 NFI
<br /> Athabasca tar sands,and coal.Motor gasolnnnes are made chiefl general.gasoline is from petroleum,shale oil, I 2
<br /> fractions into more volatile fractions y a eking processes,which convert heavier petroleum S 20
<br /> 3
<br /> by thermal or catalytic gaol c kaon.Widely usod u fuel in internal combustion K 4
<br /> ,r engines ofthespark-ignited,reciprocating type,Automotive asoline hu an .Skin
<br /> content of aromatic hydrquentocarbons 8 octane number of approximately 90.A}ugh
<br /> y contai nA and aponion high toxicity arc also associated with a high octane rating.Some absorpdoo
<br /> y WX�per
<br /> gine 90 sold a the en contain a manor proportion of tetraethyllead,which is added in oonoentratioru not exceeding 3 ml iHUvi)
<br /> enIleaa.em engine�riock"However,methyl-tat-butyl ether(MTBE)has almost completely replaced p
<br /> Other IksEgnatlons:CAS No.8006 619,benun,gasoline gasolene,motor R
<br /> hianufaeturet;Contact Vkitr,natural gasoline petrol PPG
<br /> yoar supplier or distributor.Consul latest Chanieal Week Byers'Guidecm for a suppliers list t sec
<br /> ... Cautions:Inhalation of automotive gasoline vapors can cause intense
<br /> depression,and possible fatal pulnomsry edam,Gasoline is a burning in throat and lungs,central nervous system(CNS)
<br /> dangerous fare and explosion hazard what exposed to heat and flare
<br /> Section 2. Ingredients and flccupafioilal Exposure I1lruts es
<br /> ...
<br /> � Automotive gasoline,lead-five*
<br /> 1990 OSHA PELs 1990.91 ACGIH TLVS
<br /> 8-hr TWA:300 s 1995-96 Toxicity Data*
<br /> 15 ruin STEL 500 ppm,1500 mg/ms STEL 500 1480 ns s M1II'initalation�T1CL.:900 ppm/l hr,toxic effects include sense
<br /> PPm, mg/m organs and special senses(conjunctiva irritation),behavioral
<br /> 1990 NIOSH REL (halit"intatioK'distorted perceptions),lungs•thorax,or
<br /> None established respiration(cough)
<br /> Human,eye:140 ppm/8 hr,toxic effects include mild irritation
<br /> Rat,inhalation,LC,:300 g/m3/5 mat
<br /> I.r
<br /> A typical modem gasoline composition is g0%
<br /> sulfur,phosphorus.and MTBE. Paraffins,14%aromatics,and 6%olefins.The mean benrrrie eonteat is approximately l%.Other addidves inclu,
<br /> f See NIOSH.RTECS=30M),for additional tori data.
<br /> Section 3 Physical Data
<br /> Bolling Point Ituaslly,102'F(34'Cj;after 10%distilled, Dens! /S '
<br /> (60'C);after 50%distilled,230'F(110'C);after 90%distilled "'tWater Solubility:cnsolub10.72 to 0.76 at 60 T(15.6•C)
<br /> 338'F(170'C);final boiling poin4 399 T(204'C)
<br /> Vapor Density(air=1):3.0 to 4.0
<br /> Appearance and Odor.A clear(gasoline may be colored with dye),mobile liquid with a characteristic odor recognizable at about 10 ppm inn!
<br /> ::SecE:iorii. Fi .
<br /> r and
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<br /> 5 F 43Flash In -
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<br /> ( Aatotgnition Tem rature:536 to 853 F ..
<br /> ExtinguLshing Media:Use dry clterrn'cal.carbon dioxi (2g0 456'C) LEL 13%v/v UEL:6.0%v/v
<br /> Il�but use water de,or alcohol foam u extinguishing media.Use of water may be ineffective to extinguish
<br /> spray to knock down vapors and to cool fete exposed dnuru and tanks to prevent Pressure rupture.Do not nue a solid stream of
<br /> � water since it may spread thefuel --
<br /> Unusual Fire or Explosion Hazards:Automobile gasoline is an OSHA Class IB flammtable liquid and a dangerous fire and explosion hazard
<br /> when exposed is heat and flames.Vapors can flow to an ignition source and flash back.Automobile gasoline can also react violently with
<br /> oxidizing agents. -
<br /> �+ Special Fire-fighting Procedures:Isolate hazard area and deny entry.Since fire may produce toxic fumes,wear a self-contained breathing
<br /> apparatus c-A use with a full facepiece operated in pressure-demand or itive-
<br /> eztinguished nue n P� pressue mode,roti full protective clothing.When the fire is
<br /> ornsparking took for cleanup.Be aware of runoff from fire control methods.Do not release to sewers or w
<br /> SecEon`5 :
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<br /> ChYit$'Data;:< ` waterways.
<br /> Stablllt /Poi 8
<br /> Y Ymeriratlom•Auwrrw a gasoline is stable at room temperature i n closed contsaiers
<br /> xq Hazardous polYmcrization cannot occur, under normal storage and handling conditions.
<br /> Chemical Incompatiblllttes:Automotive gasoline can react with oxidizing materials such u peroxides,nitric acid,and perchlorates.
<br /> `-' Conditions to Avoid:Avoid heat and ignition sources,
<br /> Hazardous Products orl)ernmnrm .�`_. _- •. .
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