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L <br /> V \� <br /> Material Safety Data Sheets Collection: <br /> ® Genium P1;lbllshing Corporation <br /> 1145 C&Wyn Stmt ' Sheet No.713 <br /> ` Schenectady,NY 12303-1836 USA Lead(Inorganic) <br /> ' � (518)377-88s4 <br /> _p Issued:8/90 <br /> qt <br /> Lead(Inorgank)(Pb)Description:Exists widely throughout the world in a number of arcs.Its main commercial source R 0 GentnII <br /> is ggalena(lead sulphide).Lead mineral is separated from crude ores by blast-fi mace amelfmg drowsing,or eh> vlyt�c I 4 <br /> retirtatg.Lead's used mostly at matufactmng storages batteries.Other uses are in manufacturing tertacth head and both S - 1 <br /> organic and inorganic lead compounds in ceramics,piutics,and electronic devices;in producing ammtruao t.solder, K 0 3 - 0 <br /> r. cable coveting.sheet lead,and other metal products(brass,pipes,cailking);at metallurgy;in weights and as ballast;as a <br /> chemical intermediate for lead allyls and pigments;Asa cautuction material for the tank linings,pipin&and equipment <br /> used to handle the corrosive gases and liquids used in sulfuric acid manufacturing.petroleum refining.halogenation,sul- HMIs <br /> fonation•extraction,and condensation;acid for x-ray and atomic radiation protection. H 3 <br /> 60 Other Designations:CAS No.7439-92-1,lead oxide;kid salts,inorganic;metallic lead;plumbum. F 1 <br /> Manufacturer,Contact your supplier or d'istri'butor.Consult the latest Chankdweek Brws'Guide°t for a suppliers list. R 0 <br /> Cautiooc inorganic lmd is aPamir iYvank pobort.Organic lead(for example,tarllc I 1 has severe, PPG <br /> CloctTationaly lead.) erer but different,health effects. •Ser t <br /> s �poisoningHedia due to miftalation of dust and ftrrux.Major affected organ ryttema are the nervous,blood,and reproductive <br /> r„ Ys kidneys. II11twL inert or disease may result from a severe acute short-4r long-term expo <br /> titmal' <br /> 1eI1. .a <br /> ... .:..::.. :.:.::.....}.n..ay..: •;.::,..}n4i:�,r.:.:;.:..i^!.:..::..... <br /> Y.'`.^'.�,,.':1�. { '`.i�t,L7►�... .?kaui�cn°�•{{..r`:�.y �' b°�Ciii.�,ati:'y�,.°'dz•J^�ti,}.vu.{n✓Q'�:�::ri;:�iki:3vj <br /> ...n....:.i.::. .n...n. .n...nv..v. n.:CY,�.in•.�n�;,J.a•%).. "{C\R.v.I:Qa„�Lr�.:�;:?:�.�i�� a +/J{✓.��i:?�:�f..:4v.3 <br /> Lea!(morganc)fumes and dusts as <br /> Pb,u 10096 a <br /> 1989 OSHA PELs(Lead,Ivor- 1989-90 ACGIH TLV(Lead, 1985-86 Toxicity Datat <br /> 1gamic compounds) Ino nk,fumes and dusts) Human,inhalation,TCL:10 AW affects gastrointestinal tract <br /> -hrTWA:50µghn' TLV-TWA:150µgW and liver <br /> Action Level TWA':30µghn' Human oral,TDL:450 mg/kg ingested over 6 yr affects <br /> peripheral and central nervous systems <br /> 29 CFR 1910.1025 Lead Standard 1988 NIOSH REL Rat,oral,TDL:790 mg/kg affects multigeneration reproductior <br /> Blood Lead Leve:40µgn 00 g 10-hr TWA:<100µghe <br /> •Aeon level applies to employee exposure without regard to respirator rue. <br /> L, f Sec NIOSH,RTECS(0177525000),for additional initiative,reproductive,and toxicity data. <br /> .. ... 4.. .. ...........................Sura .. .. ............ ,............{.v.. .... <br /> Stl? ..v.............•.}}:ilii{}:f.}:::::1.v:::.}}}.:................:::::::.......:iii i:..........vn .... .:::i}.:}ii}:::.n...}......::... :J}n.:::.S::.0.)}:v:i::::.i y v: <br /> Y.........................::::.:........,..::::::.::::...:................ .......:..:.,.,.::.::.,:{:.::,::. .::..:�::{.:n.::..,..:::. .:::...... ........::.::::.::::::}:}}-iii:�::..:...}::::n.:......:;.}.::::.::.:.:.:i:}:.: <br /> Bolling P <br /> oint <br /> Mel ingPoint. <br /> 6213'Ft327A'C) SpeclfkGravfty(20'C/4'C): 1134 <br /> v 3 Vapor Pr7uro: 1.77 mm"Hg at 1832'F(11X10'C) Water Solubltity:Relatively iruoluble in hot or cold water• <br /> VLscoslty:32 cp at 6213'F(3274'C) <br /> Appearance and Odor.Bluish-white•silvery,gay,very soft metaL <br /> V •Lead dissolves more easily at a low pH. <br /> on"" .. <br /> ; d} <br /> ;<re: .....a <br /> .....:..............:.::::n:�n�:........:.... ........... ....:�::::.�.�::.�.�::.,.:.:....h.....a:.r.>:....J:..d. v.................:.........n+•..m i......F....... .... .....,.....�:.:}�;;:}:li}:o::�:�:��ii:: i�;: :i': <br /> .........:...:.:>:..:...............:...................:.::::..:::::.::.::.n::.:::,)..::>;..:::..:s.....:...... a.... :..:,.::.�:... v:::,n.:n.:non:::.:}i.:J.:::.::n.:.......... r< ..:.-:..;>: <br /> Flash Point None reported Autofgnitiou Temperature:None reported LEL:None reported UEL:None reported <br /> v Extinguishing Media:Use dry chemical,carbon dioxide,water spray,or foam to extinguish fire. <br /> Unusual Fire or Explosion Hazards:Flammable and moderately explosive in the form of dust when exposed to hest or flame. <br /> Special Fire-fighting Procedures:Isolate hazard area and deny entry.Sin cz fire may produce toxic fumes•wear a self-contained breathing <br /> apparatus(SCBA)with a fall facepiece operated in the pressure-dernarlderr positive-pressure mode and full protective equipment Be aware of <br /> 6.. runoff from fire control methods.Do not release to sewers a waterways. <br /> 4 ? Re' <br /> 'y:.}e;:i:}:i::Fi'^::iy.::i'^•vn:'ii:i�:n..:,i:i:::ii:::s�Ji: <br /> on.s. R <br /> eacitx,E .,Data.: ...:.::::,.:,,..i.............:...�.n.v....:....n{.:...:.. ....a,..:..{.:}::.:{.i:.:..... :...n...... <br /> ............:......a...... <br /> .........n.........................:..............:........,......:{J:.}:::n:::::�:.).�::^::::...:::..::},::,:..�,n{.:n{::{.:.,:::is a..:�..n.:.�.�,..::�::::.�:.. ... .. <br /> Stability/Poly Lead is stable at room temperature irr closed containers under normal storage and handling conditions.It tarnishes or <br /> •c„ exposure to air.Hazardous pal�mterizition cannot ocar. <br /> Chemical Incompatlbllltks Mixtures of hydrogen peroxide+trioxane explode on contact with lead.Lead is incompatible with sodium azide, <br /> zirconium,disodium acetylide,and oxidants.A violent reaction on ignition may occur with concentrated hydrogen peroxide,chlorine trifluioridr <br /> sodium acetylide(with powdered lead) ammonium nitrate(below 200'C with powdered lead).Lead is attacked by pure water and weak organ <br /> acids in the presence of oxygen Lead is resistant tg tap wale,hydrofluoric acid,brine,and solvents. <br /> Conditions to Avofd:Rubber gloves containing lead may ignite in nitric acid <br /> Hazardous Products of Decomposition:Thermal oxidative decomposition of lead can produce highly toxic fumes of lead. <br /> ::.a... ::..::.::...: <br /> 1. <br /> {.:.:,.}:{{i.;:::.:{.:{i{i..::J}:::}::.:::::::::,{::::.:;:{.i:n{.:....:.:.::::...::::iii.:n.:.:::.:...•::.:...:.::::..::..:::,..::::::a.,}..,:;:,;...::.J::.:::::_._:n.};}:.}:;:.;>;._:.i.: <br /> seC(70fl.ti.::<RCAI"a7.aT`tl.'�afA. . . <br /> Carcinogenicity:Although the NTP and OSHA do not list lead as a carcinogen,the IARC lists it as probably carcinogenic to humans,but havi <br /> (usually)no human evidence.However,the literature reports instances of lead-induced neoplasms,both benign and malignant,of the kidney an <br /> other organs in laboratory rodents.Excessive exposure to lead has resulted in neurologic disorders in infants.Experimental studies show lead h: <br /> reproductive and teratogenic effects in laboratory animals.Human male and female reproductive effects are also documented. <br /> r.. Summary or Risks:Lead is a potent,systemic poison that affect a variety of organ systems•including the nervous system,kidneys,reproducti, <br /> system,blood formation,and gastrointestinal(GI)system.The most important way lead enters the body is through inhalation,but it can also be <br /> ingested when lead dust or unwashed hands contaminate food,drink,or cigarettes.Much of ingested lead passes through fess without absorpti <br /> into the body.Adults may absorb only 5 to 1595 of ingested lead;children may absorb a much larger fraction.Once in the body,leas enters the <br /> bloodstream and circulates to various organs.Lead concentrates and remains in bone for many years.The amount of lead the body stores <br /> v increases as exposure continues,with possibly cumulative effects.Depending on the dose entering the body,lead can be deadly within several <br /> days or affect health after many years.Very high doses can cause brain damage(encephalopathy). <br /> Medical C' ndltinne Aon,-ever.A 1...G'o.,..........r..a.e... ._.. 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