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Mr. James Taylor . - 2 - . 4 October 2007 <br /> Zero Valent Iron <br /> In April 2005, ContiGroup Companies injected zero valent iron into the second water-bearing <br /> zone, about 60 to 80 feet below ground surface, by means of hydrofracturing. Four fractures <br /> and four injections were placed at each of four injection points aligned parallel and proximate <br /> to the grain silos. Monitoring wells MW-913 and MW-106 were installed near the ends of two <br /> of the fractures. <br /> About 18 months following injection, carbon tetrachloride declined from about 300 ug/I to 130 <br /> ug/I, and chloroform declined from about 80 ug/I to about 50 ug/I, as evidenced from MW-313, <br /> adjacent to an injection point. Concentrations of these constituents in MW-913 and in <br /> MW-10B declined from 1,300 ug/I to about 800 ug/I and 500 ug/I, respectively, in the same <br /> time period. <br /> Recirculation Pilot Study <br /> In the Remedial Action Plan, ContiGroup proposes to install two extraction wells (EW-11 B and <br /> EW-1213) into the second water-bearing zone downgradient of the iron injections, install two <br /> injection wells into two of the iron injection areas (IW-BH1, and IW-BH2A), and a monitoring <br /> well between the injection wells and the extraction wells (MW-1313). The placement of the <br /> proposed wells in relation to existing wells and the iron injection points are shown on attached <br /> Figure 1. The Remedial Action Plan proposes to operate both extraction wells and injection <br /> wells concurrently. As discussed in our May 2007 meeting with you, Ms. Linda Huff, Mr. Jim <br /> Huff and me, and as reported in the Second Quarter 2007 Report for GZVI, the scale of the <br /> pilot study will be reduced to include operating only one extraction well and one injection well <br /> pair. The objective of the pilot study is to evaluate if a large scale recirculation system is <br /> feasible at this site and to update and calibrate the groundwater model. When the pilot study <br /> is completed, ContiGroup intends to apply for Waste Discharge Requirements to scale up the <br /> recirculation system to include additional extraction and injection wells. ContiGroup may <br /> choose to install the additional extraction and injection wells at this time in order to economize <br /> on mobilization costs. <br /> Considering the location of existing monitoring wells, operating extraction well EW-11 B in <br /> conjunction with injection well IW-BH2A would provide the most hydrogeologic information. <br /> The well pair will operate at 1 gallon per minute while transducers placed in MW-10B, <br /> MW-13B and EW-12B, if EW-12B is installed concurrently with EW-11 B, will record water level <br /> data. If the extraction or injection rate cannot be sustained, the extraction rate will be reduced. <br /> The transducers will continue recording until water surface equilibrium is reached. When <br /> equilibrium is reached, transducers will be removed, and water surface elevations will be <br /> measured monthly for up to three months. Regional Water Quality Control Board, Central <br /> Valley Region (Regional Water Board) staff request that ContiGroup also install a transducer <br /> in MW-4B to measure the drawdown from the extraction well, a transducer in MW-96, to <br /> measure upgradient effects of the injection well IW-BH2A, and a transducer in MW-313 to <br /> verify that the injection area is accommodating all the injectant. In order to obtain the most <br /> information from this extraction/injection well pair, proposed MW-13B should be re-located <br /> between EW-11 B and IW-BH2A, as initially proposed in the Remedial Action Plan. <br /> The pilot study is proposed to run for one year, the estimated time to circulate one pore <br /> volume. <br />