Laserfiche WebLink
In October 2005, Geomatrix conducted in-situ push-pull tests at wells M-1A and M-1 B to <br /> evaluate carbohydrate utilization rates and assess potential changes in aquifer <br /> conditions due to the addition of carbohydrate. Geomatrix injected a carbohydrate <br /> solution (composed of molasses) and a conservative tracer (bromide) injected into the <br /> wells at target depth intervals, follow by ten extraction and sampling events. <br /> The transformation of TCE to cis-1,2 DCE was observed in well M-1 B, but not in well M- <br /> 1A. Complete breakdown of TCE to ethane was not observed in the 30-day test. <br /> Selenium and arsenic concentrations in groundwater increased above background <br /> levels. In some cases, these concentrations were above the MCLs. <br /> In-situ treatment using carbohydrate injection is not feasible for treating COCs in the <br /> groundwater at the Site at this time because: <br /> • observed increases of selenium and arsenic concentrations to above-MCL levels <br /> are of concern for any anaerobic ISB treatment approach, particularly given the <br /> presence of drinking water wells with the Ripon Study Area, and <br /> • a large increase in total dissolved solids is also anticipated. <br /> Attachment A.2 includes a detailed description and assessment of the previous in-situ <br /> carbohydrate push-pull test performed at the Site. <br /> 5 SOIL VAPOR EXTRACTION (SVE) ACTIVITIES AT INDUSTRIAL AVENUE <br /> SITE <br /> Vacuum extraction is an in-situ process that recovers VOCs from soil by enhancing <br /> volatilization of contaminants within the soils into the soil vapor. A vacuum is applied to <br /> the soil which propagates laterally from the extraction wells. Contaminant vapors and <br /> liquids migrate to the extraction wells where they are brought to the surface and treated <br /> prior to discharge. <br /> Camp Dresser & McKee (CDM) installed the first soil vapor extraction wells (VE-1 <br /> through VE-5) in 1986. A pilot SVE program was initiated to test the efficiency of the <br /> system in removing TCE from the vadose zones. The Site SVE system was expanded to <br /> include a total of eight vapor extraction wells in 1992. These additional wells focused on <br /> extracting vapors from TCE- and chloroform-impacted areas near suspected chemical <br /> releases on the eastern portion of the Site. In 1998, Fluor Daniel GTI (Fluor Daniel) <br /> installed four new SVE wells and a new vapor treatment system to focus vapor <br /> extraction activities in the area of highest remaining TCE concentrations near the former <br /> decaffeination building. <br /> An estimated 880 pounds of VOCs (primarily TCE and chloroform) were extracted from <br /> the subsurface between 1988 until the discontinuation of SVE prior to 1994. The <br /> historical SVE remediation activities have resulted in remediation of the vadose zone <br /> (within the upper portion of the B-zone beneath the Site) to extent feasible. Post- <br /> remediation investigations and soil vapor sampling in 2006 through 2008 in the area of <br /> the Site confirm the lack of soil vapor impacts in shallow soil gas samples, above levels <br /> of concern with regard to indoor air exposure levels for commercial/industrial property. <br /> SVE would not be effective as a groundwater treatment technology for the Site because <br /> VOCs below the water table would have to move by diffusion to the water table interface <br /> 4 <br />