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INFORMATION SHEET 6 WASTE DISCHARGE REQUIREMENTS ORDER NO.R5-2004-XXXX DEFENSE DISTRIBUTION DEPOT SAN JOAQUIN SHARPE WASTEWATER TREATMENT FACILITY SAN JOAQUIN COUNTY Chlorine disinfection of effluent causes formation of trihalomethanes, which are priority pollutants. Treatment to reduce these in wastewater generally has not been performed, and little is known at this point on the typical impact on groundwater. DDJC-Sharpe currently operates a groundwater extraction/treatment system for volatile organic compounds that is down gradient from the WWTF, so potential groundwater degradation by trihalomethanes would be limited to groundwater beneath the facility Wastewater from the types of sources present at DDJC-Sharpe typically contains nitrogen in concentrations greater than water quality objectives, which vary according to the form of nitrogen. Degradation by nitrogen can be controlled by tertiary treatment for nitrogen reduction, and agronomic reuse on harvested crops. The effectiveness varies,but generally best practicable treatment and control should be able to control nitrogen degradation at a concentration well below the water quality objectives. The proposed interim limitation reflects water quality objectives. Waste constituents that are forms of salinity pass through the treatment process and soil profile and effective control of long-term affects relies upon effective source control and pretreatment measures. In the best of circumstances, long-term land discharge of treated municipal wastewater will degrade groundwater with salt(as measured by TDS and EC) and the individual components of salts (e.g., sodium, chloride). The proposed Order sets water quality objectives for the interim while site-specific, constituent-specific limits are developed in conjunction with a BPTC evaluation of source control and pretreatment. The next Order will likely contain effluent limits for salt components other than chloride that, if met, assure groundwater quality will be controlled to an acceptable level. Other potential constituents in wastewater that may pass through the treatment process and the soil profile include recalcitrant organic compounds (e.g., ethylene glycol, or antifreeze),radionuclides, and pharmaceuticals. Hazardous compounds are not usually associated with wastewater from the types of sources present at DDJC-Sharpe and when present are reduced in the discharge to inconsequential concentrations through dilution with domestic waste, treatment, and the implementation of effective pretreatment programs. It is inappropriate to allow degradation of groundwater with such constituents, so proposed limitations are nondetect. A discharge of wastewater that overloads soils with nutrients and organics can result in anaerobic conditions in the soil profile, which in turn creates organic acids and decreases soil pH. Under conditions of low soil pH (i.e.,below 5), iron and manganese compounds in the soil can solubilize and leach into groundwater. Discharge of residual sludge to land may also lead to increases in groundwater alkalinity and hardness to concentrations that impair the water's beneficial uses and contribute to an overall increase in TDS. Overloading is preventable. Though iron and manganese limits are set at the water quality objective, groundwater pH is expected to remain the same as background.