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Stantec <br /> L & M OPERABLE UNIT- FOURTH QUARTER AND ANNUAL 2010 SITE STATUS, <br /> REMEDIAL SUMMARY, AND GROUNDWATER MONITORING REPORT <br /> Groundwater Monitoring and Sampling <br /> January 31, 2011 <br /> 2.5.2.6 Quality Assurance/Quality Control Samples <br /> Duplicate sample QCDUP-5 was collected from L&M OU C-Zone well MW-62 during 4Q10 <br /> sampling event. A comparison of the samples is shown below. <br /> Analyte Sample # Sample # % Difference <br /> MW-62 QCDUP-5 <br /> TPHg (mg/L) 0.065 0.055 +/- 16.7% <br /> TPHd (mg/L) 0.98 0.87 +/- 11.9% <br /> TPHo (mg/L) 0.20 0.14 +/- 35.3% <br /> Benzene (mg/L) <0.0005 <0.0005 0% <br /> MtBE (mg/L) <0.0005 <0.0005 0% <br /> TBA (mg/L) <0.005 <0.005 0% <br /> 2.5.2.7 General Laboratory Notes <br /> The laboratory validation issues are consistent with the C-Zone quality assurance and quality <br /> control. Each set of issues corresponds directly with the denoted report. All laboratory reports <br /> are included in Appendix C. <br /> Validation issues with report number 75022: <br /> MS/MSD results associated with samples MW-61 and MW-63 for the analytes MtBE and TBA <br /> were outside of the stated QC limits for percent recovery. This may indicate a possible bias for <br /> the reporting accuracy. The RPD values for MtBE and TBA are within range indicating precision <br /> in reporting. The LCS percent recoveries were within QC limits, for the analytes MtBE and TBA, <br /> indicating accuracy in reporting; therefore, the reported values are considered valid. <br /> The TPHd and TPHo surrogate octacosane was out of QC limits for MW-63. This could have <br /> been due to matrix interference. The sample outlier is not anticipated to affect the reported <br /> values. In addition, RPD values are within QC limits for TPHd and TPHg demonstrating <br /> precision in reporting. <br /> 2.6 FOURTH QUARTER 2010 D-ZONE GROUNDWATER RESULTS <br /> 2.6.1 D-Zone Groundwater Gradient Data <br /> D-Zone groundwater elevations at the Site ranged from 8.62 ft below MSL in well MW-55 to <br /> 7.89 ft below MSL in well MW-73 (Table 3 and Figure 24). Groundwater flow direction during <br /> 4Q10 was to the north-northwest with an approximate hydraulic gradient of 0.001 ft/ft <br /> (Figure 24). The highest D-Zone groundwater elevation (7.89 ft below MSL) was reported in <br /> well MW-73, located in the southeast corner of the L&M OU site behind the remediation system. <br /> Historical groundwater flow direction and gradient data are summarized in Table 8, and vertical <br /> I:\Tidewater\TW Stockton(Parcel 2A-0415)\Reports\QMR\2010\4010-Annual\4Q10 and Annual QSSRQRSRQMR Stockton_F I NAL.doc 2.14 <br />