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I ORC TECHNICAL BULLETIN # I.2a I , <br /> Oxygen Release Compound,ORC® <br /> Early Proof-of-Concept <br /> Experiments in the Field <br /> After successful laboratory demonstrations, the industry's need for this innovative and <br /> effective technology prompted R EC EN ES IS to conduct several large-scale field <br /> tests of ORC. <br /> The OXYGEN BARRIER concept--involving the subsurface.placement of ORC to <br /> effect remediation of dissolved phase hydrocarbons -- was successfully demonstrated <br /> and the results published. The abstract from a study at the University of Waterloo is as <br /> follows: <br /> "A field test to evaluate the applicability of an oxygen releasing compound (ORC) to <br /> the remediation of ground water contaminated with benzene and toluene was conducted <br /> in the Borden Aquifer in Ontario, Canada. Benzene and toluene were injected as <br /> organic substrates to represent BTEX compounds, bromide was used as a tracer, and <br /> nitrate was added to avoid nitrate-limited conditions.' <br /> 'The fate of solutes was monitored along four lines of monitoring points and wells. Two - <br /> lines studied the behavior of the solutes upgradient and downgradient of two large- <br /> diameter well screens filled with briquets containing ORC and briquets without ORC. <br /> One line was used to study the solute behavior upgradient and downgradient of columns <br /> of ORC powder placed directly in the saturated zone. The remaining line was the <br /> control.' <br /> 'The results indicated that ORC in both briquet and powder form can release <br /> significant amounts of oxygen to contaminated groundwater passing by it. In the. <br /> formulation used in this work, oxygen persisted for at least 10 weeks. Furthermore, <br /> the study indicates that the enhancement of the available dissolved oxygen content <br /> of the ground water by ORC, can support the biodegradation of at least 4 mg/L <br /> each of benzene and toluene. Such concentrations are typical of those encountered <br /> at sites contaminated with petroleum hydrocarbons; therefore,these results suggest there <br /> is promise for ORC to enhance in-situ biodegradation of BTEX contaminants at sites <br /> using passive systems to contact the contaminated ground water with the oxygen <br /> source." <br /> Bianchi-Mosquera, et al. (1994). Enhanced Degradation of Dissolved Benzene <br /> and Toluene Using a Solid Oxygen-Releasing Compound, Ground Water <br /> Monitoring and Remediation, (GWMR),Winter 1994. <br />