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in the region of interest. This then presents a picture of the changing dynamics of <br /> oxygen and BTEX in the entire system over time. As can be seen in Figure 1, the <br /> oxygen mass increased to a maximum in first 3-5 days and remained relatively <br /> constant for the next thirty days. At this point, the rate of oxygen consumption <br /> increased in response to an influx of BTEX through the barrier caused by the <br /> excavation of the source upgradient of the barrier (discussed below). Field <br /> measurements are indicating the ORC®Filter Socks will have a longevity of about six <br /> months under these conditions. <br /> A significant, correlative reduction of the BTEX plume was documented. A series <br /> of contour plots illustrate the reduction of the BTEX plume as a result of oxygen <br /> migrating from the ORC® barrier. There was clear evidence of enhanced oxygen <br /> dispersion into the formation of at least 20 feet downgradient from the monitoring <br /> well network, as detailed in Technical Bulletin IV.3a. <br /> As illustrated, in Figures 2a and 2b, there was a significant reduction in BTEX mass <br /> in the treatment zone and at a significant distance away from the barrier. <br /> Concentrations of total BTEX in samples from the most downgradient well, 120 feet <br /> from the barrier, declined to Non-Detect (ND). Also, at this well, assays of aerobic <br /> microbial degraders were two orders of magnitude higher than background indicating <br /> the presence of oxygen from the ORC installation was driving bioremediation. <br /> The gasoline spill was in an area approximately 30' X 45' and located at between 50 - <br /> and 100 feet behind the barrier. Groundwater velocity was 1-2 feet per day. Project <br /> timelines dictated that the excavation was to immediately precede barrier placement. <br /> This physical activity disturbed the equilibrium of groundwater interaction with <br /> sorbed material; rainfall into the open excavation may also have been a factor. The <br /> result was that a pulse of increased dissolved phase BTEX was created and carried <br /> into the barrier, where it was detected by day 47. <br /> This effect is also seen in the contour plots. The BTEX levels then decreased as <br /> further remediation began to bring the situation under control. An increase in the rate <br /> of oxygen consumption is noted as a result. Due to the presence of an overhead <br /> power line, a 4 well section of Oxygen Barrier was installed_in the Northeast corner <br /> of the site. Based on the direction of groundwater flow, it was not subject to the pulse <br /> of BTEX from the excavated area. Consequently,the area immediately downgradient <br /> was remediated. <br /> REG EN ES IS -------------------------------------------------------------------=--------------- <br /> Bioremediation ProduCts 27130A Paseo Espada, Ste 1407, San Juan Capistrano, CA 92675 <br /> Phone: 714-443-3136 Fax: 714-443-3140 <br />