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• Semi-volatile organic compounds (SVOCs) including <br /> polycyclic/polynuclear aromatic hydrocarbons(PAHs/PNAs) <br /> • Fumigants ethylene dibromide (EDB) and 1,2-dibromo-3-chloro propane <br /> (DBCP) <br /> • Ammonia <br /> • Total phosphorus <br /> Modified Title 22 §64433 general minerals suite: - Sulfate <br /> - Nitrate Chloride- Total dissolved solids (TDS) <br /> Water samples for VOC (including fumigant) analysis will be collected with the low- <br /> flow pump at a rate of 100 ml/min or less, and carefully transferred to VOAs (with the <br /> appropriate preservative), ensuring the absence of headspace. All samples will be <br /> labeled, sealed and stored on ice (4C) according to laboratory requirements. Samples <br /> for diesel-range and heavier hydrocarbons, semi-volatile and non-volatile constituents <br /> may be collected at flow rates of 1 liter/min, and transferred into their appropriate <br /> containers (with preservatives as required), labeled and stored on ice (4C) for delivery <br /> to the laboratory. <br /> Non-disposable sampling equipment will be decontaminated between wells by washing <br /> with a non-phosphate detergent, rinsed twice with tap water and final-rinsed with <br /> deionized or distilled water. One rinsate blank will be collected and analyzed per <br /> sampling event. One duplicate groundwater sample will be collected and analyzed for <br /> every ten submitted for the same analysis. One trip blank (per sampling event), <br /> prepared by the laboratory, will accompany the groundwater samples back to the <br /> laboratory. Standard chain-of-custody protocols will be employed for sample <br /> identification and transfer of possession. Field personnel will be mindful of short <br /> holding times, and ensure samples are delivered to the laboratory in sufficient time for <br /> extraction and analysis. <br /> Analyses for the constituents listed above will be as follows: <br /> • VOCs: EPA Method 8260B <br /> • TPH-cc: EPA Method 8015B <br /> • As and Hg: EPA Method 6010B <br /> • Cr VI: EPA Method 218.6 <br /> • SVOCs(incl. PAHs/PNAs): EPA Method 8270C <br /> • Fumigants (EDB, DBCP): EPA Method 504.1 <br /> • Ammonia: Standard Method(SM)4500 NH3 B/C(EPA 350.2) <br /> • Total phosphorus(P): SM 4500 P B/E(EPA 365.3) <br /> • Sulfate (SO4),Nitrate(NO3) and Chloride(Cl): EPA Method 300.0 <br /> • Total Dissolved Solids(TDS): SM 2540C(EPA 160.1) <br /> Purge water will be stored in labeled drums until laboratory results have been received, <br /> at which time the groundwater and drums will be disposed in conformance with <br /> appropriate regulations. <br />