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s <br /> Ms. Angela Lee <br /> Huntbrook Holdings,LLC <br /> February 12, 2014 <br /> Page 11 <br /> Approximately 155 gallons of groundwater were generated during the well development (125 gallons) <br /> and initial sampling (30 gallons) of monitoring wells MW-4, MW-6, MW-7 and MW-8 during the <br /> • fourth quarter 2013. The water was transported under non-hazardous manifest to Instrat's treatment and <br /> disposal facility in Rio Vista,California. Copies of the disposal manifests are included in Enclosure O. <br /> Conclusions/Recommendations <br /> Based on the laboratory analytical results for the initial groundwater samples collected from monitoring <br /> wells MW4, MW-6, MW-7 and MW-8 on December 3, 2013, it appears that the lateral extent of <br /> dissolved petroleum hydrocarbon constituents and TCE in groundwater have been adequately assessed <br /> at this time. Concentrations of BTEX, fuel oxygenates (MTBE, ETBE, DIPE, TAME and TBA), and <br /> naphthalene in groundwater were all below the laboratory's reporting limit. The absence of volatile <br /> constituents in groundwater is consistent with an old fuel release as is suspected at the subject property. <br /> Low levels of TPHg were reported in monitoring wells MW-6 and MW-7 at concentrations of 77 and <br /> 220 pg/L, respectively. The TPHg reported in MW-6 was noted by the laboratory as being primarily <br /> compounds not found in typical gasoline, and after further discussion with lab personnel, is most likely <br /> a result of the TCE and PCE which fall into the reporting range for TPHg. In the future, RDM will <br /> request the laboratory to report both TPHg and Gasoline Hydrocarbons in order to differentiate between <br /> what is actually gasoline and TCE/PCE. Following silica gel cleanup, TPHd was only reported in <br /> • monitoring well MW-4 at a concentration of 84 µg/L, and was noted by the laboratory as being higher <br /> boiling point hydrocarbons, not typical of diesel. The highest concentration of TCE was reported in <br /> monitoring well MW-6, at a concentration of 4.6 µg/L, which is below the California Drinking Water <br /> Maximum Contaminant Level(MCL)of 5.0 µg/L. <br /> Dissolved tetrachloroethene (PCE) was reported in one offsite monitoring well sample at a <br /> concentration that exceeds the California Drinking Water MCL of 5 µg/L. PCE was reported in <br /> monitoring well MW-6 at a concentration of 36 gg/L. This well (MW-6) is located hydraulically <br /> crossgradient to downgradient (depending on the time of year) from the subject property. The PCE <br /> concentration reported in offsite monitoring MW-6 is significantly greater than any concentration <br /> reported in the onsite monitoring wells. The highest concentration reported onsite was in monitoring <br /> ti well MW-3 at a concentration of 9.0 µg/L on September 17,2013. It is RDM's opinion that the elevated <br /> PCE concentration reported in monitoring well MW-6 is most likely attributed to an offsite source such <br /> as an old dry cleaning facility. There are many well documented cases of impacts to sanitary sewers <br /> from historic illegal discharges of dry cleaning solvents. Before doing any further groundwater <br /> assessment for PCE, RDM recommends conducting a records review to identify any potential historic <br /> dry cleaners within the vicinity of the subject property and the location of the sanitary sewer along East <br />• Main Street. <br /> The lateral and vertical extents of petroleum hydrocarbon and VOC constituents in soil onsite have been <br /> adequately assessed. Based on the previous consultant's soil data(Enclosure C)and RDM's results for <br /> boring RDM-1 (Table 1), the majority of the residual impact (secondary source) appears to remain in <br />. the northeast corner of the site, in the vicinity of the former fuel island and UST(that was located on the <br /> east side of the former station building), at depths beginning at approximately 12 to 16 fbgs and <br /> extending down to the water table (48 to 52 fbgs). In soil boring RDM-1, the highest benzene <br /> concentration was detected at 3.3 mg/kg at a depth of 38 fbgs and the highest TPHg concentration was <br /> detected at 2,260 mg/kg at a depth of 18 fbgs. These results are similar to the previous consultant's <br /> results for soil boring SB-4(Figure 2). <br />• <br />