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SUBSURFACE SOIL.AND GROUNDWATER ASSESSMENT REPORT <br /> LABORATORY ANALYSIS OF SOIL AND GROUNDWATER <br /> Table 4 summarizes the concentrations of petroleum compounds detected by laboratory analysts <br /> in soil and groundwater <br /> A total of 11 soil samples were analyzed for the presence of TPHG, and BTEX by EPA Methods <br /> 1 8015 and 8020, and MTBE and associated oxygenates by EPA Method 8260 The soil sample <br /> obtained from soil boring TP-4 at 15 feet bgs had a concentration of 11 parts per billion (ppb)of <br /> MTBE 3 Laboratory analysis did not identify concentrations above the detection limits for <br /> TPHG,BTEX, DIPE,ETBE, TAME and TBA in the 11 soil samples analyzed <br /> A total of 5 groundwater samples were analyzed for the presence of TPHG and BTEX by EPA <br /> Methods 8015 and 8020,and MTBE and associated oxygenates by EPA Method 8260 <br /> Groundwater samples were below the detection limits for all analyzed constituents, with the <br /> exception of 1,300 ppb of MTBE in TP-4, and 14 ppb of MTBE in the groundwater sample <br /> obtained from TP-5 <br /> ' CONCLUSIONS AND RECOMMENDATIONS <br /> CONCLUSIONS FROM INVESTIGATION <br /> Soil analysis and field observations during the April 7, 2000 UST removal did not indicate a <br /> significant mass of residual petroleum hydrocarbons remaining beneath the former tank This <br /> conclusion is consistent with the results of ESA's recent subsurface soil and groundwater <br /> assessment Low MTBE concentrations in soils appear localized at the north and south ends of <br /> the former UST excavation MTBE concentrations were not detected in soil samples collected <br /> 1 east or west of the excavation perimeter MTBE concentrations were not found to have migrated <br /> vertically in soil to depths below groundwater(approximately 15 feet) <br /> ' Analytical results of the groundwater samples further substantiates the conclusion that the impact <br /> from residual MTBE appears localized at the north and south ends of the former UST excavation <br /> Non-detectable levels of MTBE in groundwater samples collected east and west of the UST <br /> ' excavation confirm the restricted extent of impacted groundwater The highest MTBE <br /> concentration detected in soil was collected during tank removal activities at the southern end of <br /> the tank,however MTBE was not detected in groundwater samples collected beneath the center <br /> ' of the former excavation in the estimated downgradient direction Impact to groundwater <br /> therefore appears localized around defined low levels of MTBE remaining in soil Lateral <br /> migration of groundwater at the site would be very slow, given the very stiff to hard clayey silts <br /> ' identified in this assessment Considering the consistency of these fine-grained soils, hydraulic <br /> conductivity for the shallow groundwater could range from 1x10-4 to 1x106 centimeters per <br /> ' second or between 10 and 100 feet per year 4 In addition, the presence of a thick clayey zone <br /> impedes vertical groundwater migration between the water table investigated, and the lower <br /> source aquifer Typically, shallow groundwater is of low quality and not extracted for public <br /> 3 Parts per billion or ppb is equivalent to micrograms per kilogram or ug/kg to soil or micrograms per Liter or mg/L in <br /> water <br /> 4 Hunt,Geotechnical Engineering Investigations Handbook,McGraw Hill,New York,New York, 1984 <br /> ' Subsurface Soil and Groundwater Assessment ESA/200252 <br /> 1081 W Mendocino Avenue Stockton Califomia 10 August 25 2000 <br />