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GROUNDWATER TEC.INOLOGY <br /> STANDARD OPERATING PROCEDURE <br /> CONCER14ING WATER SAMPLING METHODOLOGY <br /> SOP 9 <br /> Prior to water sampling, each well shall be purged by <br /> pumping a minimum of four well volumes or until the <br /> stabilization of temperature, <br /> discharge water indicates <br /> conductivity,and pH. 1'f the well is evacuated before <br /> `our well volumes are removed or stabilization is <br /> achieved, the sample should be taken when the water <br /> level, in the well recovers to 80% of its initial level. <br /> Retrieval of the water samole, sample handling and sample <br /> preservation shall be conducted in accordance with <br /> Groundwater Technology Laboratory Standard Operating <br /> Procedure (GTL SOP 10) concerning Sampling For Volatiles <br /> in Water" . The sampling equipment used shall consist of <br /> a teflon and/or stainless steel samplers, which meets <br /> EPA regulations. Glass vials with teflon lids should be <br /> used to store the collected sampies. <br /> To insure sample integrity, each vial shall be filled with <br /> the sampled water such that the water stands above the lip <br /> of the vial. The can should then be quickly placed an the <br /> vial and tightened securely. The vial should then be <br /> checked to ensure that air bubbles are not present prior <br /> to labeling of the sample. Label information should <br /> include a sample identification number, ;ob identification, <br /> date, time, •type of analysis requested and the sampler' s <br /> name. Chain-of-Custody forms shall be completed as per <br /> Groundwater Technology Laboratory Standard Operating <br /> Procedure (SOP 11) concerning Chain o- Custody. <br /> 1 The vials should be immediately placed in high quali'_y <br /> coolers for shipment to the laboratarv. The coolers <br /> should be packed with sufficient ice or freezer ?ask: to <br /> s which <br /> ensure that the samples are kept below 4C- Samp_es <br /> are received at the G,oundwa_e~ Technoiocy Laborator': <br /> above 10 C. will be considered substandard. To Minimize <br /> sarple degradation the prescribed analysis shall take <br /> glace within saven days o sample collection unless <br /> soecially prenzred acidified v'-ais are used. <br /> To minimize the potential for cross contamination between <br /> wells, all the well development and water sampling equ-p- <br /> ment which contacts the grou,:dwater shall be cleaned <br /> between each well samDling. As a second precaun'onary <br /> _ measure, the wells shall be sampled in order of increasing <br /> contaminant concentrations as established by previous <br /> analysis. <br />