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INFORMATION SHEET <br /> CITY OF STOCKTON <br /> REGIONAL WATER QUALITY CONTROL PLANT <br /> SAN JOAQUIN COUNTY <br /> want to be held liable for temperature violations if it is due to other dischargers, the p:rmit <br /> requires the City to evaluate how to best monitor compliance with the limits. <br /> pH- <br /> EPA regulations (40 CFR 401.17) state that allowable pH effluent limitations under continuous <br /> monitoring may allow for excursions from the pH range given that: (1) the total time during <br /> which the pH values are outside the required range of pH values shall not exceed 7- hours and <br /> 26 minutes in any calendar month; and (2) no individual excursion from the range of pH values <br /> shall exceed 60 minutes. This regulation essentially allows pH limitations to be exceeded 1 <br /> percent of the time. <br /> Effluent from the plant is chlorinated to meet the coliform limitation, and then the plant <br /> strategy is to dechlorinate with sulfur dioxide to eliminate all chlorine, and leave a residual of <br /> dechlorination chemical. However, overdosing with dechlorination chemicals can occasionally <br /> depress the effluent pH below the minimum 6.0. Caustic can be added to bring the effluent pH <br /> back into compliance. The effluent is discharged to the San Joaquin River through two siphon <br /> pipes which run from the chlorine contact channel over the levee to the river. Control systems <br /> are wired so that detection of pH excursions at the inlet to the siphon will break the siphon. <br /> The City monitors pH continuously, and estimates that from detection of an excursion to <br /> complete breaking of the siphon takes approximately 30 seconds. Stockton submitted data <br /> regarding pH excursions for 1993. The data showed that there were 13 excursions during the <br /> year, 62% occurred for less than a minute, and the remaining excursions were during times <br /> when there was no effluent discharge into the river. The data indicates that the excursions are <br /> short-term and of small magnitude. <br /> The Order requires that the discharge not have a pH less than 6.0 nor greater than 8.5, and that <br /> excursions above or below the limits not exceed 3 minutes, respectively. Also, the total <br /> duration of excursions may not exceed 1% of the discharge time within a reporting period. <br /> This limit is more restrictive than allowed by EPA, but, with operation of the siphon shutoff <br /> control system, should easily be achieved. A provision is also included to require the pH <br /> control system and the siphon discharge shutoff be operated to prevent excursions outside the <br /> range of 6.0-8.5, to the extent it is operationally feasible. <br /> Settleable Solids- <br /> The permit requires that effluent settleable solids not exceed a daily maximum of 0.1 mg/1. <br /> The limit is an extension of the Basin Plan requirement that "Waters shall not contain <br /> substances in concentrations that result in the deposition of material that causes nuisance or <br /> adversely affects beneficial uses." The 0.1 mg/1 limit represents a numerical value which, if <br /> not exceeded, guarantees compliance with the narrative standard. <br />