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Work Plan and Time Schedule for Analyses of Background Gmuadwater Quality <br /> City of Stockton Regional Wastewater Control Facility <br /> Page 3 <br /> SM the groundwater gradient is toward the Stockton groundwater pumping depression to the east. The <br /> configuration of the groundwater gradient is consistent with recharge of the shallow water table from the <br /> river. <br /> 5.0 THE GROUNDWATER QUALITY DATABASE <br /> The current water quality database primarily consists of quarterly field parameters and groundwater <br /> sample data collected since 2003 from a network of 18 monitoring wells shown on Figure 2.MW-4 is no <br /> longer active and there are currently 17 active monitoring wells. The data include salinity parameters, <br /> nitrate as nitrogen and ammonia as nitrogen and contain about 20 independent values for each parameter <br /> at each site. The data sets for three (3) salinity indicators, field electrical conductivity (EC Field), <br /> laboratory electrical conductivity (EC Lab) and total dissolved solids (TDS) have approximately 350 <br /> independent measurements for each parameter in all wells. Data for nitrogen parameters included many <br /> non-detects. Supplemental testing of groundwater,pond water, and agricultural drainage water for general <br /> minerals was performed in 2006. The supplemental data are included in the full database shown in Table <br /> 2. The current dataset does not include information on sodium (Na), boron (B), chloride (Cl), dissolved <br /> iron (Fe) and dissolved manganese (Mn); these parameters were added to the required monitoring suite <br /> for Order No.R5-2008-0154. <br /> Normal distributions are required for most useful statistical treatments used to deme exceedance <br /> probabilities and background threshold values. The salinity data were analyzed for normal distributions <br /> using the Lilliefors test for high sample counts (l) and the Shapiro-Wilk test(N<50)in ProUCL, an EPA <br /> statistical program. ProUCL output reports are included in Appendix 1. Each of the three salinity- <br /> indicator datasets were combined for all wells and tested for a normal distribution. None of them were <br /> normally distributed. This indicates that multiple populations of data are present among the different <br /> wells and time periods represented in the data. The preliminary"take home"message from this statistical <br /> information is that the site as a whole cannot be well characterized by one set of salinity data from these <br /> monitoring points. <br /> When each salinity parameter was tested in each well, we found most of the EC Field data fit normal <br /> distributions (except MW-17), but that in approximately half of the wells EC Lab and TDS data were not <br /> normally distributed. The fact that some wells exhibited normal populations of EC Lab data while others <br /> did not could be data variability from sample handling. The EC Field is the preferred parameter if <br /> measuring equipment is routinely calibrated, because EC can be affected during transport to the <br /> laboratory. The fact that almost all wells had normally distributed populations of EC Field data indicates <br /> that parametric (predictable) statistics may be applicable at an intra-well level. This also indicates that <br /> some variability between TDS constituents within wells could be due to seasonal or other causes that are <br /> non-random and would need further statistical analysis to evaluate suitable methods to evaluate <br /> background conditions.Table 3 summarizes the results of the Shapiro-Wilk intra-well testing. <br /> 6.0 HYDROCHEMISTRY <br /> Information from Report of Groundwater Conditions in the Vicinity of the City of Stockton Regional <br /> Wastewater Control Facility Oxidation Ponds prepared by Condor in 2006 was updated through <br /> December 2008 (see Table 2). Chemical data are plotted in Appendix 2. Additional analyses, performed <br /> for this Work Plan,have led to the following discussions. <br /> EC Field and TDS exceed the secondary drinking water standards in all wells except MW-11 and MW-14 <br /> located east of, and near the river (see Table 4). The highest values are in samples from MW-1, MW-2, <br /> and MW-5 with mean EC values over 2,000 micromhos per centimeter(equivalent to 2,000 µS/cm). The <br /> upgradient well MW-15 to the south has a mean field EC of 1,453 µS/cm and the downgradient well <br /> MW-16 to the west has a mean field EC of 1,525 µS/cm. EC Field and TDS are both correlated with <br /> i� CONDO <br />