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WASTE DISCHARGE REQUIREMENTS ORDER NO.R5-2002-0213 14 <br /> U.S.DEPARTMENT OF DEFENSE <br /> DEFENSE LOGISTICS AGENCY <br /> DEFENSE DISTRIBUTION DEPOT SAN JOAQUIN <br /> SHARPE GROUNDWATER REMEDIATION SYSTEM <br /> SAN JOAQUIN COUNTY <br /> appropriate criteria. This Order retains the weekly average effluent limitation for total lead of <br /> 3.2 µg/L (ppb) from the previous Order as an interim limitation pending collection of new data. <br /> 24. Previous Order No. 95-258 included a monthly median effluent concentration limitation for <br /> mercury of 0.012 gg/L (ppb). The Basin Plan does not provide a numeric water quality <br /> objective for mercury. The current USEPA water quality criteria for mercury, for protection of <br /> human health for consumption of both water and organisms, is 0.050 µg/1. The USEPA is <br /> currently reviewing the ambient water quality criteria for mercury and may recommend more <br /> stringent criteria,based in part on organism uptake and bioaccumulation. The Delta has been <br /> listed as an impaired water body pursuant to Section 303(d) of the Clean Water Act for mercury, <br /> based on fish tissue concentration and not water column toxicity. The California DHS has issued <br /> health warnings regarding the consumption of fish from Delta waterways. While the SSJID <br /> Canal and French Camp Slough are not identified as impaired for mercury on the California <br /> 303(d) list, additional loading resulting from the discharge from the DDJC-Sharpe facility has <br /> the potential to cause or contribute to the impairment resulting from mercury bioaccumulation in <br /> the Delta. A TMDL for mercury is currently scheduled to be completed by December 2005. <br /> At Section 2.1.1 the SIP states: "For bioaccumulative priority pollutants for which the receiving <br /> water has been included on the CWA Section 303(d) list, the RWQCB should consider whether <br /> the mass loading of the bioaccumulative pollutant(s) should be limited to representative, current <br /> levels pending TMDL development in order to implement the applicable water quality standard'. <br /> Since mercury is known to bioaccumulate in fish and is a pollutant that is causing impairment of <br /> the Sacramento-San Joaquin Delta, the discharge must not cause or contribute to increased <br /> mercury levels in fish tissue to meet the requirements of the anti-degradation policy described <br /> in <br /> SWRCB Resolution No. 68-16 and the anti-degradation provision in 40 CFR 131.12 a 1 . The <br /> intent of this Order is to include an interim performance based effluent mass limitation for <br /> mercury. <br /> Results of limited `ultra-clean' sampling and analysis conducted by the Discharger using EPA <br /> Method SW 1631 indicate GWTP effluent mercury concentrations ranged from < 0.0005 µg/L <br /> (ppb)to 0.011 µg/L(ppb). These concentrations do not exceed the CTR human health criteria. <br /> Current mercury data is not sufficient for establishment of an interim performance based <br /> limitation. This Order requires the Discharger to collect data necessary to establish an interim <br /> performance based effluent mass limitation. <br /> Performance-based effluent limits for mercury are typically established as follows: 1) The <br /> average monthly effluent mercury concentration is calculated by adding all detected . <br /> concentrations and one-half of the reported detection levels of all non-detectable mercury <br /> concentration results; 2) From the average monthly mercury concentration and average monthly <br /> flow, a monthly mercury mass discharge is calculated; and 3) A total mass for all months is then <br /> totaled, and an average annual mass discharge is calculated. <br />