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tC-SHADRIFS.6/WPADD.3 <br /> 05/17/90 <br /> 1 have increased the solubility of the arsenic-bearing minerals, <br /> resulting in arsenic concentrations in excess of the EPA MCL. <br /> 3. The arsenic concentrations in the groundwater beneath SHAD may <br /> be the result of naturally occurring mineral assemblages in <br /> contact with groundwater which reflects conditions unique to <br /> the San Joaquin Valley. <br /> Identifying the contamination mechanism will have important implications <br /> for the FS that follows the RI performed at SHAD. For instance, the <br /> volume of groundwater to be treated and the treatment process itself <br /> will be more accurately modeled after the investigation is complete. <br /> A computerized database currently is being compiled to help analyze the <br /> groundwater chemistry data that have been collected at SHAD over the <br /> past 5 years. The analysis is incomplete, but it appears that different <br /> mechanisms are acting on the transport of arsenic in the groundwater <br /> than act on VOCs. For instance, plumes of VOCs have been mapped, and <br /> the migration path can be predicted. In addition, the incidence of the <br /> ' VOC plume with downgradient wells can be calculated with accuracy. <br /> However, arsenic data suggest that excessive levels of dissolved arsenic <br /> occur only at certain wells, and at those wells the arsenic <br /> ' concentrations in groundwater have fluctuated between less than 50 ppb <br /> and more than 500 ppb in less than 3 months (e.g. , monitor well 407A) . <br /> Arsenic moves between suspended and dissolved species over very short <br /> horizontal distances (less than 25 ft) in less than 3 months. <br /> This conclusion affects remediation decisions because the behavior of <br /> arsenic will require treatment on a much closer interval than if arsenic <br /> were advectively transported. <br /> Water quality data collected elsewhere in the San Joaquin Valley, <br /> specifically at the Tulare Lake Drainage District 275 miles south of <br /> 3 <br />