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Mr. Ken Gillies <br /> Gillies Trucking <br /> 3931 Newton Road, Stockton <br /> Page 2 of <br /> the Modesto Formation will be cleaned by repeated rising and falling of groundwater <br /> elevation and that the resulting impacted groundwater will be cleaned by sorption in the <br /> various Riverbank units. Based on these results and a reported decrease of diesel- <br /> impacted groundwater concentrations from 190,000 parts per billion (ppb) to <br /> approximately 10,000 ppb over seven years, UCE re-recommended site closure as a <br /> low-risk site. UEC also concluded that the mass of TPH-d impacting soil, is slightly less <br /> than 42,500 pounds. <br /> The EHD has several concerns with the work performed and the conclusions presented. <br /> With a mass on the order of 42,500 pounds of TPH-d in soil of the Modesto subjected to <br /> periodic inundation by groundwater, the EHD is concerned about the potential impact to <br /> more than 30 water supply wells within 2,000 feet of your site identified by your <br /> consultant. The leaching test was designed to utilize impacted soil samples from the <br /> Modesto Formation, but as no impacted samples were recovered from the two soil <br /> borings, one soil sample identified as Modesto aquitard and three Riverbank soil <br /> samples were spiked with diesel fuel to a concentration of 100 milligrams per kilogram <br /> (mg/kg)to conduct the test. <br /> The EHD is concerned with the results and interpretation of the leaching test as <br /> conducted for several reasons: <br /> • Intuitively, fresh diesel will have more shorter chain hydrocarbons than <br /> weathered diesel, and therefore a somewhat higher solubility in water; <br /> • The residence time of the spiked diesel on the soil samples is significantly less <br /> than that for the impacted site soil, which may limit absorption and adsorption <br /> into microscopic pores in mineral grains and into such naturally occurring organic <br /> matter as is part of the soil; and <br /> • TPH-d concentrations in some of the Modesto Formation samples near the base <br /> of the Modesto sand unit ranged up to nearly 20,000 mg/kg (GT-22) in contrast to <br /> the 100 mg/kg spiked samples; <br /> • The concentrations of TPH-d in soil samples collected from GT-22, <br /> approximately 6.5 years after GT-10 was drilled were not significantly lower than <br /> those in the GT-10 samples despite at least 3 additional years of immersion in <br /> groundwater; and <br /> • The results of the leaching test as performed implies a nearly 100% leaching <br /> potential for diesel in the diesel-impacted soil, which in turn indicates an <br /> extremely high risk associated with the nearly 42,500 pounds of diesel estimated <br /> to be in soil on the site. <br /> A low-risk from impacted soil left on site at site closure is more commonly associated <br /> with a very low leaching potential for the impacted soil. UEC implies that the reduction of <br /> dissolved TPH-d in GT-10 water samples from nearly 190,000 ppb in 1999 to <br /> approximately 10,000 ppb in 2006 validates the leaching model and results. The EHD <br /> notes that the 190,000 ppb detected in GT-10 water in March 1999 declined to 48,000 <br /> ppb in June 1999 and declined to 7,000 ppb by October 1999. The September 2000 <br /> sample had 180,000 ppb TPH-d, but three months later the water had 1,000 ppb TPH-d. <br /> The 10,300 ppb TPH-d in GT-10 in October 2006 has increased to 33,000 ppb in March <br />