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ell <br /> Marla D. Guensler <br /> 15 July 1992 <br /> Exxon Company, U-S.A. --'Y Page 2 <br /> EA disagrees with Shell's interpretation of the data for the following reasons and would like to <br /> point out several items of concern: <br /> 1. Shell's tank closure samples contained TPH-g at concentrations up to <br /> 4,300 mg/kg and benzene at concentrations up to 10 mg/kg. These <br /> concentrations indicate the presence of soils saturated with hydro- <br /> carbons. <br /> 2. That no petroleum hydrocarbons were found in water samples obtained <br /> from monitoring wells MW 1--3 is not surprising, because none of these <br /> wells are downgradient of any potential sources, either the former tank <br /> field or the product piping and certainly not from the point from where <br /> the 4,300 mg/kg sample was collected. Even monitoring well MW4 is <br /> not placed directly downgradient of the impacted soils identified during <br /> the removal of the former tanks. Additionally, a general lowering of <br /> groundwater concentrations is expected to'occur as the groundwater <br /> elevation continues to rise. Hydrocarbon concentrations decrease as the <br /> water level rises because the hydrocarbons:are filtered from the water I <br /> by the "clean" soils that they are coming into contact with and by the <br /> influx of water. <br /> 3. Regarding the soil hydrocarbon concentratior'ts,EA contacted both Steve <br /> Schneider of San Joaquin County Public Health Services and Jacqueline J <br /> Doub of Aegis Environmental, Inc. in July of 1991 and informed them <br /> of the large historical fluctuations in groundwater elevations in the area <br /> and that of the first seven monitoring wells installed across the street <br /> at the Exxon site only one sample contained TPH-g at concentrations <br /> greater than the method detection limit of 10 mg/kg (60 mg/kg) and no <br /> BTEX compounds were detected at concentrations greater than the <br /> detection limit of 0.05 mg/kg. In spite of this knowledge, the only well <br /> to be placed by Shell nominally downgradient of the identified source <br /> of hydrocarbons was drilled only to a depth of 40 feet. This means that <br /> only about half of the potentially impacted soils have been investigated. <br /> 4. The low concentrations of volatile hydrocarbons measured in the soil <br /> vapor extracted from well VEW-2 are not indicative of low <br /> hydrocarbon concentrations in the soil. According to Shell's "Results <br /> Report for Air Monitoring of Extended Pilot Vapor Extraction Test," <br /> dated 7 February 1992, soil vapor was extracted only from well <br /> VEW-2,except for a 2-hour test performed on well VEW-1. As shown <br /> i in cross-section A-A' (Figures 1 and 2), the screen and sanded section <br /> of Shell's vapor extraction well was placed mostly in the gravel backfill <br /> of the former tank field. This causes a serious short-circuiting problem <br /> through the porous backfill, and while this would be effective at <br /> cleaning up the gravel backfill, it will have only a small influence on <br /> E <br />