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M <br /> es'Vt}ts <br /> SGS,i kS and MS0 R Every twenty <br /> n ideal matrix nalyzed <br /> Tie Meaning ante in a le,then a <br /> daeumefit method Po to a purified water same <br /> is to es is ad ethod accuracy <br /> of the t-SS e#fec{of sample <br /> The purpose cOncentration5fis aalepresentatiOn a# rn dor- the m temple is <br /> samples, a known far the LC ©uplrcate is 1$$analysed,a aT aed to t rio <br /> The percent-recovery atnx Spike es are <br /> Matrix SpikelM every tweri e��ins of anat`ft and SSD are 1 s%s a <br /> urpose of the darmence 'For <br /> corrc tar the two array <br /> Thep aa`'ers a betpieerr the <br /> e� l�e n,,etrlx Spi ed taercesrt-re t drf#ererrc <br /> matrti eq o s n analyz rcerr- if LGS <br /> selec cif the sample,tyre acaurar*and the Pe 0b anaWs's motors <br /> aliqui3ts ethod 30%,tar our$��'ccuracy P <br /> entatyons°f etrod PrectiSlon a Of +I- Outside of a all samples <br /> repres tion of m <br /> repfe5enta accepte"nce r is performing policy+s to <br /> note r�analy�ed' data <br /> have an the method Our general p le can <br /> t <br /> ,,cover pf this range' n a same <br /> LCS peresn - utslde must be aualifs 1e reasa , <br /> recoveries fall o tar arrnal and the <br /> Or certain analGS insult lf' estimated l#the <br /> and data f failing L 30°la are n ,atrrx <br /> With a biased Or range or+I- b ttre 'amp s <br /> ass" <br /> ed as potentially .overy the analyss <br /> e Flagg sr1#+�ar'tly atfecte #act 4n r# <br /> rnustb that fall witrin tsig to a matrix to determ4ne et# is not <br /> Ovaries t°�t may indica varies method <br /> SQ percent-rec lg is consider <br /> rcent-recc ar the <br /> liplSlM f that same ave ar%be ca pared to tG5 Cavy problem, <br /> analysis o that recovery slag an aac the <br /> results fall outside eaoveries,satrlx is caps r than 5x <br /> rcQnt le a uaI to Or greats tri% <br /> MS{,p�ISl3 Pe ut the same accurately easure of ma in the un- <br /> snethmg at Sfl should be q <br /> Centrations a �lSlt�i be a reliable nre cancentratian <br /> measuring con d sample to As tha anal rrieanin9 once <br /> cOncentratiOn or ptiyCe 000G) he spike concentration, <br /> has less sample, <br /> the spiked Method S an <br /> JAoWever, centration Presant'n the analytes s half t <br /> e con erformance Pot spiked high resent in the <br /> ethOd P $ h a rrnarice- <br /> analyt the recovery d sample are a nape cancentraticans <br /> interaction Orle gpes UP, s Ike ure of method pedQ rpt 40 ug/L <br /> samp Sin the un- P relative tO a <br /> Spiked Unts re ►nsign"licant re use{ul areas trau() Z u b, <br /> nGentration are nota s ike cancers <br /> tw <br /> analyte splke amo vanes or the$pike sarx�pte$$p <br /> �/1SINi eGi#�igher�4i'centcatiQn <br /> rearm reap LGSM Sand MSO e rn a erence vfirth the pt�r Qa <br /> and pe a Spiked anal atrrbuied to ti le -spiked sample dat2� <br /> risig a are ,n rc,�sstons <br /> w protocol�arepsrelpa sa'mpl��et+13t a r ratans pies leties have no rope <br /> #ar Most arrayt s ),.Aslde angl e cone MSIMSCD To <br /> MSIMS'D recoverie Spike frau► the Matti% <br /> ant of the p this Circumstance, t seed as <br /> measurers ecrtythat in Number)th protectNurrlb$r <br /> procedures$p Kitf ldent►#kation les tram <br /> lrsled by it associated same <br /> validatiOrr f samples� with the <br /> The following is the list°licate Samples <br /> atria T&�Truke Ck ng) Sam le <br /> Spiker 001 &'T 3t �ktt� <br /> 127960- �asflGiated , Ott <br /> ate <br /> am ►e 'lCt�i 1D priv <br /> S -1 <br /> S tike -3 <br /> 492756- ark ander <br /> 42781-p1r�-4 <br /> 4275'2372-p4 <br /> 42766-42, <br /> rte_ <br />