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S9200-06-82 ATTACHMENT B— 1'22 (CAM-17) Metals NIOSH Gutoe to Chemical Hazards-2005
<br /> Formula: CAS#: RTECS#: IDLH:
<br /> 7Synonyms/Trade
<br /> ;b 7440-36-0 CC4025000 50mg/m3 (as Sb)
<br /> DOT: 1549 157 (inorganic compounds, n.o.s.);2871 170 (powder);
<br /> 3141 157 (inorganic liquid compounds, n.o.s.)
<br /> Names:Antimony metal,Antimony powder, Stibium
<br /> Exposure Limits: Measurement Methods
<br /> NIOSH REL*: TWA 0.5 mg/m3 (see Table 1):
<br /> OSHA PEL": TWA 0.5 mg/m3 NIOSH 7301, 7303,
<br /> [*Note: The REL and PEL also apply to other antimony compounds (as Sb).] P&CAM 261 (II-4)
<br /> Physical Description: Silver-white, lustrous, hard, brittle solid;scale-like crystals; OSHA ID121, ID125G, ID206
<br /> or a dark-gray, lustrous powder.
<br /> Chemical &Physical Personal Protection/Sanitation Respirator Recommendations
<br /> Properties: (see Table 2): (see Tables 3 and 4):
<br /> MW: 121.8 Skin: Prevent skin contact NIOSH/OSHA
<br /> BP: 2975°F Eyes: Prevent eye contact 5 mg/m': 95XQ/Sa
<br /> Sol: Insoluble Wash skin:When contam 12.5 mg/m': Sa:Cf/PaprHie
<br /> FI.P: NA Remove:When wet or contam 25 mglm': 100F/SaT:Cf/PaprTHie/ScbaF/SaF
<br /> IP: NA Change: Daily 50 mglm': Sa:Pd,Pp
<br /> Sp.Gr: 6.69 §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba
<br /> VP: 0 mmHg (approx) Escape: 100F/ScbaE
<br /> MLT: 1166°F
<br /> UEL: NA
<br /> LEL: NA
<br /> Noncombustible Solid in bulk form,but a moderate explosion hazard in the form of dust when exposed to flame.
<br /> Incompatibilities and Reactivities: Strong oxidizers, acids, halogenated acids
<br /> [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen.]
<br /> Exposure Routes, Symptoms,Target Organs (see Table 5): First Aid (see Table 6):
<br /> ER: Inh,Ing, Con Eye: Irr immed
<br /> SY: Irrit eyes, skin, nose,throat, mouth; cough;dizz;head;nau, Skin: Soap wash immed
<br /> vomit, diarr; stomach cramps; insom; anor; unable to smell properly Breath: Resp support
<br /> TO: Eyes, skin,resp sys, CVS Swallow: Medical attention immed
<br /> • • Formula: CAS#: RTECS#: IDLH:
<br /> !. . • As (metal) 7440-38-2 (metal) CGO525000 (metal) Ca [5 mg/m3(as As)]
<br /> Mnversion: DOT: 1558 152 (metal); 1562 152(dust)
<br /> Synonyms/Trade Names: Arsenic metal:Arsenia
<br /> Other synonyms vary depending upon the specific As compound. [Note: OSHA considers "Inorganic Arsenic"
<br /> to mean copper acetoarsenite &all inorganic compounds containing arsenic except ARSINE]
<br /> Exposure Limits: Measurement Methods
<br /> NIOSH REL:Ca (see Table 1):
<br /> C 0.002 mg/m3 [15-minute] NIOSH 7300, 7301, 7303,
<br /> See Appendix A 9102,7900
<br /> OSHA PEL: [1910.1018]TWA 0.010 mg/m3 OSHA ID105
<br /> Physical Description: Metal: Silver-gray or tin-white, brittle, odorless solid.
<br /> Chemical & Physical Properties: Personal ProtectionlSanitation Respirator Recommendations
<br /> MW: 74.9 (see Table 2): (see Tables 3 and 4):
<br /> BP: Sublimes Skin: Prevent skin contact NIOSH
<br /> Sol: Insoluble Eyes:Prevent eye contact V: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba
<br /> FLP:NA Wash skin:When contam/Daily Escape:GmFAg100/ScbaE
<br /> IP: NA Remove:When wet or contam
<br /> Sp.Gr:5.73 (metal) Change:Daily See Appendix E (page 351)
<br /> VP:0 mmHg (approx) Provide:Eyewash
<br /> MLT: 1135°F(Sublimes) Quick drench
<br /> UEL: NA
<br /> LEL: NA
<br /> Metal:Noncombustible Solid in bulk form,but a slight explosion hazard in the form of dust when exposed to flame.
<br /> Incompatibilities and Reactivities:Strong oxidizers,bromine azide
<br /> [Note: Hydrogen gas can react with inorganic arsenic to form the highly toxic gas arsine.]
<br /> Exposure Routes, Symptoms,Target Organs (see Table 5): First Aid (see Table 6):
<br /> ER: Inh,Abs, Con, Ing Eye: Irr immed
<br /> SY: Ulceration of nasal septum, derm,GI disturbances, peri neur, Skin: Soap wash Immed
<br /> resp irrit, hyperpig of skin, [cart] Breath:Resp support
<br /> TO: Liver,kidneys,skin, lungs,lymphatic sys (lung &lymphatic cancer] Swallow: Medical attention immed
<br /> Stockton 6-Lane,Task Order No.82 Caltrans Contract 06A1141,EA 10-03A1001
<br /> Project No.S9200-06-82 B-1 of 8 December 2009
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