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e <br /> Quik Stop Station No. 76 March 18,2009 <br /> Stockton,California Soil Gas Investtigation Work Plan <br /> Task 1 Retain a C57-licensed drilling and mobile laboratory contractor experienced <br /> in soil gas investigations; obtain permits, if required, from the local <br /> regulatory agency; notify Underground Services Alert (USA) for <br /> identification of underground utilities in the immediate Site area; update the <br /> Site-specific Health and Safety Plan to include soil gas investigation work. <br /> Task 2 Advance temporary soil gas sampling probes (SG-1 through SG-5) to depths <br /> '1 of 5 to 6 feet below surface grade (bsg); utilize hydrated bentonite to seal the <br /> ground surface around the drive rod to prevent ambient air intrusion from <br /> occurring; subsequent to sampling, abandon all borings by backfilling with <br /> bentonite/cement grout; finish the surface with a flush concrete plug. <br /> Advance the initial soil gas probe at the location that is likely to yield the <br /> highest constituent concentrations; at all sampling points, allow 26inutes o <br /> elapse after the sampling probe is landed, opened, flow tested at the target <br /> depth and the surface is sealed for subsurface conditions to equilibrate prior I <br /> to collecting soil gas samples; steadily draw soil gas samples into new 50 ml C: ✓� <br /> sampling syringes over at least 15 seconds. <br /> Conduct purge volume test at the initial soil gas sampling point for evaluation all <br /> of the appropriate purge volume for the remaining locations; evaluate purge <br /> volume for the sampling apparatus tthati cl des the annular space around the <br /> open sample probe and the sample tubing�c o'nduct purge volume tests of 1; 3 <br /> and 7 apparatus volumes; purge and sample at flow rates less than 200 <br /> 4i <br /> milliliters per minute lmllmm); abort sampling if maximum attainable flow <br /> rates are less than I O ml/qn or vacuum exceeds 10 inches of mercury; select <br /> the purge volume that provides the sample that contains the highest <br /> constituent concentrations; if two or more purge test samples contain similar <br /> concentrations, purge 3 volumes prior to collecting each sample. <br /> Conduct leak testing at each sampling location utilizing 1,1-difluoroethane <br /> (DFA) as tracer compound; dispense leak test compound at any location <br /> along the sampling apparatus where ambient air could enter the sample flow; <br /> if tracer compound is detected, evaluate the cause of the leak and correct <br /> before continuation of sampling; collect one field blank and one duplicate <br /> sample to check for procedural and analytical reproducibility/precision, <br /> respectively; analyze blank and duplicate samples utilizing the same methods <br /> as field samples. -ru- Y14t (r cl <br /> Analyze soil gas samples in the mobile lab within 30 minutes of collection <br /> for: total petroleum hydrocarbons as gasoline (TPHg), the volatile aromatic <br /> compounds benzene, toluene, ethylbenzene, total xylenes (BTEX), the fuel <br /> oxygenate methyl-t-butyl ether (MTBE) and for the leak compound DFA-by <br /> EPA Method 8260B; utilize analytical reporting limits at or below the values <br /> for the selected analytes as listed in the shallow soil gas Table 2 of California <br /> 5GI WP Mar09 <br /> Project No.7076.15 3 HORIZON ENVIRONMENTAL INC. <br />