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UNOCAL <br /> Page 2 <br /> Monitoring wells should be installed off site and downgradient with these deeper screened <br /> intervals to show the lateral and vertical extent of the groundwater contamination. <br /> Contaminant levels in groundwater from 25 to 50 feet bsg on site appear to have reduced since <br /> 1988 when MW 1, MW2, and MW3 were first installed. This probably is due to dilution and <br /> dispersion from the increased amount of water in this interval resulting from the heavy <br /> precipitation in recent years (1996 and 1997) and recharge, as well as the vapor extraction <br /> conducted in 1996. In February 1999, downgradient and off site MW7 (screened interval 35—59 <br /> feet, although quarterly sampling reports show total depth 55 feet) evidenced benzene and MTBE <br /> for the first time. This may be evidence that the contamination is continuing to migrate. <br /> Comparing the levels of contaminants in the soil samples from VW2(drilled in February 1992)with <br /> the soil samples from NPI (drilled in January 1999)which are about 20 feet apart, it appears that <br /> vapor extraction was a viable remedial alternative. The highest levels of soil contamination <br /> remaining on site appear to be below 50 feet from surface. The depth to first water when the <br /> vapor extraction system was operating was about 35 feet below grade. Vapor extraction well 2 is <br /> screened from 24 to 51 feet bsg, so it appears that vapor extraction was successful in remediating <br /> the soil below water. <br /> As previously discussed in PHS/EHD correspondence, feasibility tests must be conducted to <br /> determine the most cost-effective remedial alternative. Site conditions have changed since the <br /> vapor extraction tests were performed in 1992 and 1996. Vapor extraction and air sparging <br /> should be evaluated since they have proven to be effective in areas of Stockton. <br /> On page 22 of the February 26. 1999 report, there is discussion about the Basin Plan not <br /> differentiating between Primary and Secondary MCLS and that wells with constituents above an <br /> MCL are not considered safe for drinking. While the Basin Plan may not differentiate between <br /> Primary and Secondary MCLS, the laws and regulations governing public drinking water certainly <br /> differentiate between MCL classifications. Primary MCLs are based on health concerns and <br /> secondary MCLs are based on constituents that may adversely affect the taste, odor or <br /> appearance of the drinking water. In addition, best available treatment technologies differ for the <br /> constituent of concern. <br /> On page 7 of the February 26, 1999 report, there is discussion about the saline front in the <br /> Stockton area and references a map from the 1997 San Joaquin County Flood Control and Water <br /> Conservation Report. It appears from that map that the saline front changes with the level of <br /> groundwater. In 1990 first groundwater was about 50 feet bsg and the site was within the saline <br /> front. In 1985 and 1997 when first groundwater was about 30 feet bsg, the site was not within the <br /> saline front. <br /> On page 24 of the February 26, 1999 report, it is noted that the pH of the water from NPI is <br /> greater than the pH of the water from MW2 and MW10. NP1 is smaller in diameter than the other <br /> monitoring wells which made its' development difficult. The pH of the water from NP1 reduced as <br /> the well was developed on February 1, 1999. Also, the pH of the water from NP1 during its' <br /> purging on February 4, 1999 was similar to the pH of the water from MW4, MWS, MW7, MW8, or <br /> MW9. <br />