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While proof of concept at the field level was achieved in the Waterloo test, it remained <br /> necessary to show efficacy in an actual groundwater pollution scenario. Soil and ground <br /> water contamination, due to release of gasoline from an underground storage tank, was <br /> initially identified and investigated at the Jennifer Mobile Home Park by the North <br /> • Carolina Division of Environmental Management Additional site characterization was <br /> completed by the Civil Engineering Department of North Carolina State University for <br /> further definition of the plume and to design the oxygen barrier system. The following <br /> describes the environmental conditions, remedial action and results of oxygen barrier <br /> installation, within the 137 day investigative period <br /> The plume, which was the target of remediation efforts, was characterized at a point 150 <br /> feet downgradient of the source At this point, BTEX concentrations were 8 ppm in a <br /> region 120 feet wide and 10 feet deep The oxygen concentration within the plume was <br /> zero and the redox potential was -50 mV. Outside the zone of contamination oxygen <br /> levels were 1-4 ppm in a +50 mV redox background The conductivity of the aquifer <br /> is approximately 76 feet/day; velocity was approximately 9 feet per day The influent <br /> BTEX levels rose during the course of the experiment by a factor of three to five times <br /> OXYGEN BARRIERS were constructed intersecting the plume 150 ft downgradient <br /> from the source The permeable barrier system consists of 22 fully screened PVC wells <br /> 5 feet on center in a line perpendicular to the plume The wells were 6 in in diameter <br /> and 10 ft in depth from the water table. The ORC was mixed in concrete to from <br /> briquets and was installed in filter fabric socks that were hung inside the PVC wells <br /> .' Monitoring wells were installed upgradient and downgradient of the barrier <br /> Groundwater samples were monitored for dissolved oxygen, BTEX concentration, pH, - <br /> redox potential, and other parameters at various times over 137 days <br /> The ORC Oxygen Barrier reduced BTEX contamination from source levels of X20 <br /> mg/L to X0.1 mg/L in 137 days; B was reduced to within <1% of standard (8000 <br /> ppb to 34 ppb) and T, E and X were below standard. Oxygen levels in source well <br /> were maintained between 9 and 17 ppm. <br /> In must be noted that the ratio of oxygen to carbon was only 2.1 and the wells were only <br /> loaded to partial capacity Also, incoming BTEX levels tripled during the course of the <br /> trial, and at the end of the experiment, free hydrocarbon product was found in one of the <br /> wells This raised the possibility that other similar zones may have existed <br /> downgradient between the barrier wells and the monitoring points <br /> The current product consisting of a sand/ORC mixture in a polyester sock is both denser <br /> and made to occupy more of the available well diameter Along with some ORC quality <br /> improvements it can deliver three times the oxygen as was delivered in <br /> this early experiment The oxygen barrier was replenished with the current product and <br /> results will be completed and published in early 1996 <br /> i <br />