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1.Assembly and review of existing geologic,hydrologic,and water-quality data.Existing well logs,water-level,and <br /> water-quality data will be compiled and assembled into a Geographic Information System(GIS)using ARCINFO <br /> and ARCVIEW software.Although much of the development of the GIS will occur early in the study the GIS will <br /> be used,updated,and revised throughout the study and will be the basis for a 3-D visualization.Data within the GIS <br /> will be used to evaluate the areal extent of high-chloride water,and to draw geologic sections through the study area <br /> that define the areal and vertical extent of aquifer deposits along three selected flowpaths from sources of recharge <br /> to discharge areas near the delta.The areal extent of high-chloride water and the geologic sections will be used to <br /> define data gaps that guide test-drilling and installation of observation wells.Existing water-quality data in the area <br /> of high-chloride water and along the three study flowpaths will be used to define the quality of native ground water <br /> and its geochemical evolution prior to collection of new data. <br /> 2.Collection of geochemical and geophysical data.Water chemistry data will be collected from up to 60 existing <br /> production and the 12 observation wells installed as part of this study.The data will be used to define the source, <br /> movement,and age of water from wells and the areal and vertical extent and source of high-chloride water to wells <br /> along the three study flowpaths.Samples will be analyzed for major ions,nutrients,selected trace elements,and the <br /> stable isotopes of oxygen and hydrogen by the U.S.Geological Survey National Water Quality Laboratory(NWQL) <br /> in Denver,CO.Quality assurance will be provided through the use of blank and replicate samples collected as part <br /> of the study. <br /> Selected trace elements,including bromide,iodide,boron,and barium,will be used in conjunction with chloride <br /> data to determine the source of high-chloride water in wells using methods originally developed by Piper and other <br /> (1953)in the Long Beach area of southern California and extended to other parts of coastal California by Izbicki <br /> (199 1)and Izbicki and others(2002).The stable isotopic composition of water from wells also will be used to <br /> determine the hydrologic(oceanic versus meteoric)and evaporative history of the water using methods developed <br /> by Izbicki(1996).Selected samples from 20 wells will be analyzed for tritium and its decay product helium-3 to <br /> determine the age of younger(less than 50 years)ground water.Selected samples from 20 other wells will be <br /> analyzed for carbon-14 and carbon-13 to determine the age of older(greater than 50 years)ground water that does <br /> not contain tritium.Selected samples from 20 wells will be analyzed for noble gasses to determine the recharge <br /> mechanism—focused recharge from stream infiltration versus areal recharge from precipitation or irrigation return. <br />