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Diamond Pet Food&Ripon Energy October 25,2017 <br /> Third-Quarter 2017 Groundwater-Monitoring Report Page 2 of S <br /> CONCLUSIONS <br /> The past disposal of plant process water by the former paper making facility was responsible for <br /> some of the elevated TDS levels measured in the semiperched aquifer over most of the site, <br /> however, since the facility's conversion to a pet food manufacturing facility, plant effluent has <br /> never exceeded the 800 mg/L effluent limitation for TDS. The elevated TDS levels in the <br /> semiperched aquifer in the northeastern quadrant of the site, however, which have been up to <br /> three times higher than effluent TDS levels, are likely caused by the eucalyptus trees' <br /> concentrating effect on TDS.1 The elevated TDS levels observed along the western portion of <br /> the site,particularly in the southwest corner of the site,probably reflect the infiltration of higher <br /> TDS water originating at the City of Ripon's WWTF encroaching onto the DP/Ripon Energy <br /> site. <br /> The elevated nitrate concentrations along the western portion of the DP/Ripon Energy site (OB- <br /> 1 and OB-5)probably reflect the infiltration of water originating at the City of Ripon's WWTF <br /> encroaching onto the DP/Ripon Energy site. The origin of elevated nitrate concentrations in <br /> OB-26 and OB-28 is unknown, although it is unlikely to be from plant activities, as these points <br /> are generally upgradient of the plants. Nitrate concentrations have fluctuated in these wells in <br /> the recent past from highs of 26.6 mg/L in OB-4 (July 1993), 88 mg/L in OB-26 (July 2008), <br /> 200 mg/L and in OB-28 (January 2008) to their current nitrate concentrations of 6.7 mg/L in <br /> OB-4, 29 mg/L in OB-26 and 51 mg/L in OB-28. The current nitrate levels in OB-26 and OB- <br /> 28 are approximately 5 to 11 times higher, respectively, than the 4.5 mg/L average effluent <br /> nitrate level in ASB-2 pond water for 2016.2 <br /> Overall, groundwater quality is generally stable or improving under most of the site. <br /> SITE DESCRIPTIONS AND OPERATIONS <br /> DIAMOND PET FOOD PROCESSORS OF RIPON CALIFORNIA, LLC <br /> DP uses dry ingredients, oils, fats, and fresh meat to manufacture its products. Dry ingredients <br /> consist of cereal grains, dry animal proteins, and vitamin and mineral supplements. The dry <br /> ingredients are delivered in bulk or bagged form. The bagged ingredients are stored in a dry <br /> warehouse. The bulk ingredients are stored in bins and silos. Fats and oils are stored in liquid <br /> tanks within a contained tank farm. The fresh meat is shipped in reusable totes and stored in a <br /> cooler room. <br /> The dry ingredients first are mixed together in a three-ton mixer, and then transferred to a <br /> hammer mill for more extensive grinding to turn into a mash. The mash is then sent to the <br /> extrusion process where the fat/oil and fresh meat are added. The extrusion process uses time, <br /> temperature, heat and pressure to cook the product. The product is cooked to a minimum of <br /> 190°F. This process creates a very small amount of scrap which is reworked or sent to an <br /> appropriate disposal facility. <br /> The product is sent from extrusion to a dryer, where it is dried for about 30 minutes. The <br /> product then moves to a series of coaters that apply fat/oil and natural flavors. The product is <br /> 1 G.S.Jorgensen,Kenneth H. Solomon,and V. Cervinka,March 1993,Agroforestry Systems for On-Farm Drain <br /> Water Management. <br /> z Lawrence&Associates,January 31,2017, Combined Annual and Fourth-Quarter 2016 Groundwater-Monitoring <br /> Report,p. 3. <br /> 010107.09 Task 3 Lawrence&Associates <br /> W:CLIENTSIDiamond Pet Foods 1010107.01-Groundwater Monitoring)Groundwater Monitoring1201 713Q201 713Q quarter 2017 report.docx <br />