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Additional Instructions: • In case of skin contact Go to the nearest emergency shower if contaminated. Yell <br /> for assistance and rinse for 15 minutes, removing all articles of clothing to ensure contaminate is completely <br /> removed. Follow up at Acute Care/Employee Health as appropriate. In case of eye contact Go to the nearest <br /> emergency eyewash. Yell for assistance and rinse for 15 minutes. Follow up at Acute Care/Employee Health. <br /> Small Spill If a small spill occurs inside a fume hood or near other local exhaust ventilation, lab personnel <br /> should be able to safely clean it up by following standard spill clean-up procedures:•Alert people in immediate <br /> area of spill • Increase ventilation in area of spill (open fume hood sashes) • Wear personal protective <br /> equipment, including utility grade nitrile gloves • If available, cover spill with acid/base neutralizer • If <br /> neutralizer is not available, confine spill to small area with adsorbent material (pads, vermiculite) • Collect <br /> residue,place in container, label container, and dispose of as hazardous waste• Clean spill area with soap and <br /> water <br /> Larger Spill • Call EHS for emergency assistance • Evacuate the spill area • Post someone or mark-off the <br /> hazardous area with tape and warning signs to keep other people from entering • Stay nearby until emergency <br /> personnel arrive and provide them with information on the chemicals involved <br /> 4. Waste (Procedures, Storage, and Disposal): <br /> Hazardous Waste must be properly labeled and may be stored in a designated Satellite Accumulation area for up <br /> to 9 months. One container per waste stream is permitted at a time. When the container becomes full or reaches <br /> its 9 month accumulation limit,request a waste disposal pickup by emailing Risk Management <br /> riskmana eg mentkpacific.edu. <br /> Additional Instructions: Acids and Bases must be neutralized before discarding. Hazard-free salt solutions <br /> from acid-base neutralization may be disposed of down the drain. Common examples include the waste of <br /> hydrochloric acid or sulfuric acid neutralized by sodium hydroxide.Hazardous salt solutions, e.g.heavy metal <br /> salt solutions such as Ni, Cr,Pb, etc.,MUST be collected in the aqueous waste container in the laboratory. <br /> IF NOT SURE,ASK SUPERVISOR HOW TO DISPOSE. <br /> 5. Details of Process <br /> Any waste in the laboratory that has been identified as acidic(pH<7)or basic (pH>7)must be neutralized <br /> to pH 7. <br /> The solution shall be neutralized in a wide-neck container(e.g. beaker)that is not filled more than 50%of its <br /> total volume. <br /> During neutralization, add only small quantities of acid/base (as appropriate)to the solution to be neutralized. <br /> Stir the solution continuously(can be manually with glass rod or mechanically with a magnetic stirring plate <br /> or slow shaker). <br /> In case concentrated acids or bases have to be neutralized,monitor the temperature of the solution to be <br /> neutralized and provide adequate cooling(ice bath) if needed. This prevents overheating,boiling and <br /> overflowing of the solution out of the container. <br /> Progress of neutralization should be monitored with small samples applied to general-purpose pH-paper until <br /> green H 7). <br /> 6. Training <br /> All personnel are required to complete all General Safety and Lab Safety training requirements and any additional <br /> training sessions specific to equipment and chemicals in the work area. PI's or Lab supervisors shall work with <br /> the EH&S and the Learning and Development Departments to ensure all necessary trainings are selected and <br /> completed by lab personnel. <br /> Additional Training Required: All personnel are trained to safely use concentrated acids and bases and to <br /> properly neutralize these solutions. <br />