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J. R. Simplot, Lathrop -6- I August 2UU <br /> San Joaquin County <br /> a qualified professional and submitted in hard copy to this agency for review and <br /> concurrence before undertaking these types of activities. <br /> 2) The email received on 23 March 2007 was informative and briefly described the <br /> assessment and remedial work that took place in response to the ammonium sulfate <br /> release. The work plan portion of the email states: "When we get results that are <br /> about as low as we think we are going to get, we will resample and analyze them <br /> both in our lab and at a certified outside lab. We will also conduct additional <br /> background sampling adjacent to the soil contamination areas." Although, I had <br /> discussed with Mr. Yanak on the telephone what activities were planned for future <br /> assessment and remediation of the impacted areas, the actual work plan needs <br /> greater detail and justification for the planned assessment work. The work plan <br /> should include detailed figure(s) showing known areas of impact, proposed and <br /> existing soil sample locations, data table(s) showing all data collected to date <br /> (analytical results, depth of samples and amount of soil excavated). The work plan <br /> must detail how background samples are to be collected and used for defining the <br /> limits of impact and justify any future excavation work. The work plan also needs to <br /> address potential impacts to groundwater. For groundwater assessment, the work <br /> plan should propose and detail proposed assessment borings, installation of <br /> monitoring wells (three wells at a minimum) or at least grab groundwater sample <br /> analysis. Please prepare a work plan that addresses the above comments <br /> regarding ammonium sulfate release to the surface water drainages and submit it to <br /> this office by 12 September 2007. <br /> 3) The analytical results presented in the email work plan were analyzed by J. R. <br /> Simplot's laboratory. While these results are acceptable to help guide the <br /> investigation and remedial work, final soil and groundwater confirmation samples <br /> that will be used to define the limits of impact must be analyzed by a California — <br /> certified laboratory. Please indicate in the above requested work plan a statement <br /> that all soil and groundwater confirmation samples will be analyzed by a California — <br /> certified laboratory. <br /> 4) Based on nitrate studies reviewed by the Regional Water Board, soil cleanup goals <br /> for niP:rates must achieve less than either 100 milligrams per kilogram (mg/!gig) or <br /> established background levels for protection of human health and the environment. <br /> Groundwater cleanup levels for nitrate must achieve a level less than 10,000 ug/L <br /> (the Public Health Goal) and/or established background levels. Groundwater <br /> ammonium results should not exceed 1,500 ug/L (based on taste and odor) or <br /> established background levels. Ammonium soil cleanup goals can be based on <br /> either a waste extraction test method using deionized water where the extraction <br /> analysis does not exceed 100 ug/L or established background levels. J. R. Simplot <br /> must establish background levels of nitrate and ammonium in soils and <br /> groundwater, which will likely serve as the cleanup goals for the impacted area. <br /> Section 20415 of Title 27 <br /> (http://www.waterboards.ca.gov/cwphome/land/docs/t2797m.pdf) provides guidance <br /> on how to establish background concentrations. <br />