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Bert E. Van Voris _ 10 - 17 September 2004 <br /> Supervising Engineer <br /> Notwithstanding the issue of the blanket drain discharge and the extent to which it is <br /> composed of impounded wastewater, evidence that impounded wastewater is impacting <br /> groundwater is seen in the changing quality of groundwater in MW-16, a shallow <br /> monitoring well 250 feet downgradient of the dam. Since wastewater impoundment, <br /> quarterly monitoring of groundwater passing through this well has shown an increase in <br /> TDS and sodium, as well as in calcium, magnesium and alkalinity. The RWD cites the <br /> low permeability of native soils under the reservoir(estimated at 10"6 to 10-7 cm/sec) as <br /> evidence that the increased concentrations of TDS and sodium in MW-16 cannot be <br /> attributable to the percolation of impounded wastewater. The RWD does not <br /> acknowledge that native soils under the reservoir also contained significant deposits of <br /> highly permeable material—material that had to be excavated in the area of the dam prior <br /> to its approval by the Division of Dam Safety.10 <br /> Also,the RWD does not mention the increasing concentration of calcium, magnesium and <br /> alkalinity in MW-16. The 3 June 2004 letter from Musco's consultant dismissed the trend <br /> of increasing calcium, magnesium and alkalinity in MW-16 as evidence of organic <br /> overloading and instead attributed it to "natural weathering (mineralization of groundwater <br /> interacting with the aquifer matrix) and/or increases in carbon dioxide levels in soil due to <br /> past agricultural uses." While this is not the forum for a full discussion of the causes for <br /> elevated calcium, magnesium, and alkalinity in groundwater impacted by high-organic <br /> discharges, Regional Board files do contain substantial evidence that decomposition of <br /> organic material within the soil profile,particularly the release of carbon dioxide gas, has <br /> the potential to accelerate soil weathering. The elevated concentrations in groundwater of <br /> calcium, magnesium, and other soil minerals suggest this has occurred. Until irrefutable <br /> evidence is presented to indicate otherwise(e.g., from a tracer dye study), it will remain <br /> my professional opinion that monitoring data from MW-16 indicates impounded <br /> wastewater has affected groundwater quality. <br /> The matter of the reservoir's permeability and containment integrity must be resolved as <br /> part of the current WDRs and TSO, as well as to consider Musco's proposed use of the <br /> reservoir for treatment. This use has the potential to impact groundwater for organics and <br /> decomposition byproducts, especially as a sludge layer will form and thicken along the <br /> reservoir's bottom. It will be necessary to implement BPTC measures to prevent these <br /> impacts. For example, either the reservoir must be equipped with a liner to preclude the <br /> infiltration of waste constituents to soil or the wastewater discharged to the reservoir must <br /> be treated to a level that will not release organics in a mass that will cause elevated <br /> concentrations of decomposition byproducts in groundwater. <br /> Water Balance <br /> Introductory Comments: Water balances submitted in support of a land discharge must <br /> employ the maximum anticipated discharge flow and,through identification of available <br /> disposal area, storage, percolation losses, etc., demonstrate that there is sufficient effluent <br /> storage and disposal area to accommodate the maximum discharge flow without <br /> discharging offsite during exceptionally wet years (i.e., 100-year return period). <br />