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Chemwatch:4650.17 Page 5 of 12 Issue Date:06/27/2017 Version No:6.1.1.1 Phosphate Test Solution#2 Print Date:06/21/2019 stannous Tin,and inorganic compounds, US ACGIH Threshold Limit Not Not Values(TLV) chloride, excluding Tin hydride,as Sri- 2 mg/m3 Available Available Not Available anhydrous Oxide and inorganic compounds US OSHA Permissible stannous Tin,inorganic compounds(except Not Not Exposure Levels(PELs)- chloride, 2 mg/m3 Not Available Table Z1 anhydrous oxides)(as Sn) Available Available I EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 GLYCERINE 96% Glycerine(mist);(Glycerol;Glycerin) 45 mg/m3 860 mg/m3 2,500 mg/m3 STANNOUS CHLORIDE Stannous chloride;(Tin(II)chloride(1:2)) 9.6 mg/m3 65 mg/m3 640 mg/m3 SOLUTION Ingredient Original IDLH Revised IDLH GLYCERINE 96% Not Available Not Available STANNOUS CHLORIDE SOLUTION 100 mg/m3 Not Available I MATERIAL DATA Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard"physically"away from the worker and ventilation that strategically"adds"and"removes"air in the work environment.Ventilation can remove or dilute an air contaminant if designed properly.The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. General exhaust is adequate under normal operating conditions.Local exhaust ventilation may be required in specific circumstances.If risk of overexposure exists,wear approved respirator.Correct fit is essential to obtain adequate protection.Provide adequate ventilation in warehouse or closed storage areas.Air contaminants generated in the workplace possess varying"escape"velocities which,in turn,determine the"capture velocities"of fresh circulating air required to effectively remove the contaminant. Type of Contaminant: Air Speed: solvent,vapours,degreasing etc.,evaporating from tank(in still air). 0.25-0.5 m/s (50-100 f/min) aerosols,fumes from pouring operations,intermittent container filling,low speed conveyer 100-20000 f/min.) Appropriate engineering transfers,welding,spray drift,plating acid fumes,pickling(released at low velocity into zone of ( controls active generation) (100 direct spray,spray painting in shallow booths,drum filling,conveyer loading,crusher dusts,gas 1-2.5 m/s discharge(active generation into zone of rapid air motion) (200-500 f/min.) grinding,abrasive blasting,tumbling,high speed wheel generated dusts(released at high initial 2.5-10 m/s velocity into zone of very high rapid air motion). (500-2000 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1:Room air currents minimal or favourable to capture 1:Disturbing room air currents 2:Contaminants of low toxicity or of nuisance value only. 2:Contaminants of high toxicity 3:Intermittent,low production. 3:High production,heavy use 4:Large hood or large air mass in motion 4:Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point(in simple cases).Therefore the air speed at the extraction point should be adjusted,accordingly,after reference to distance from the contaminating source. The air velocity at the extraction fan,for example,should be a minimum of 1-2 m/s(200-400 f/min)for extraction of solvents generated in a tank 2 meters distant from the extraction point.Other mechanical considerations,producing performance deficits within the extraction apparatus,make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Continued...