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cot.,hern- Coatings .0. Box 180 Sumter, SC 28150 FMERGENC1 PHONE NO. 716-873-6000 ((7 days. ) NFORMATION PH.. NE NO. 803-775-6351 (M-F8Spm ET) DOT EMERGENCE 1800)255-3924 (24h(s) H.M.I.S. 0LTH 2• ,A IMMAB I L I TY 2 REACTIVITY 0 These ratings should be user' only as part of fully implemented ` !.I.S. pro0ram. SECTION ! . DATE OF PREPARATION 6/ 2 0/ 9 1 TRADE NAME R U S T A L 0 Y E N A Safety Orange MANUFACTURER CODE I.D. 86-0499 4 Y- 4 4 - 1 :SECTION 11 HAZARDOUS .7INGREDIENTS - -_ — ALLOWABLE SARA VP GBY T CAS NO. EXPOSURE LEVEL 313 mm Ho 0 INGREDIENT W PPM MG/CU.M. MPPCF SKIN 20 DEG.( TITANIUM DIOXIDE 13463.67.7 TLV -TWA 10 10 OSHA-PEL LEAD CHROMATE 5 7758.97-6 TLV -TWA 0.0500 X OSHA-PEL 0.0500 OSHA-CEIL 0.1000 MINERAL SPIRITS 64742.88-7 TLV -TWA 100 525 2 525 OSHA-PEL LFL 1.0 100 UFL 7.0 LEAD COMPOUNDS < 1 7439-92-1 TLV -TWA 0.1500 X OSHA-PEL 0.0500 LFL = LOWER FLAMMABILITY LIMIT PERCENT U F L = UPPER FLAMMABILITY LIMIT PERCENT SKIN = SKIN ABSORPTION MUST BE CONSIDERED AS A ROUTE OF EXPOSURE C - CEILING= ALLOW. EXPOSURE LEVEL SHOULD NOT BE EXCEEDED FOR ANY TIME PERIOD MFR = MANUFACTURER RECOMMENDED EXPOSURE LIMIT STEL = SHORT TERM EXPOSURE LIMIT X - SARA 313 = CHEMICAL IS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF TITLE I I 1 OF S . A . R . A . 40 CFR PART 372 .. __ _- SECTION [!! HEALTH =INFORMATION' r EFFECTS OF SHORT TERM OVEREXPOSURE SWALLOWING Can cause gastrointestinal irritation, nausear and vomiting. Aspiration of material into lung may cause chemical pneumonitis which can be fatal. INHALATION May cause nose or throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion. EYE May cause eye irritation SKIN May cause d e f a t t i n g and irritation of the skin. EFFECTS OF REPEATED OVEREXPOSURE Repeated and prolonged overexposure to relatively insoluble chromates may cause lung cancer. Chronic overexposure to lead may result in severe damage to blood forming nervous, urinary and reproductive systems. Some common symptoms of chronic overexposure include loss of appetite, metallic taste in the mouth, anxiety, constipation, nauseaweakness, insomnia, headache, muscle and joint pain, fine tremors, numbness, dizziness, Ihyperactivity and colic. Occupational exposure to lead is regulated by OSHHA 29 CFR !910.1025. Prexisting kidney conditions may be aggravated by exposures to lead. Reports have associated prolonged and repeated occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be h a r m f u l o r f a t a l. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTK Titanium dioxide IS NOT listed as a potential carcinogen by the National Toxicologyy Program, the International Agency for Research on Cancer] OSHA, or A.C.G.I.H- Dry titanium dioxide in a 24 -month inhalation study with rats revealed a significant increase in benign and malignant lung tumors in the group exposed to 2 5 0 m g / M 3 respirable Ti02 dust. At lower exposure levels, this significant effect was not observed. The normal clearance mechanisms of 'the lungs may have been overwhelmed at the250m9/M3 exposure level, and this may have contributed to the o c c u r e n c e of carcinogenicity. These results may not be directly relevant to the workplace where occupational exposure limits are observed. At the TLV the Ti0 manufacturer concludes that there is no significant hazard for man. Chromium and certain chromium compounds are listed as potential carcinogens by the National Toxicology Program Lead chromate has been listed as a potential animal carcinogen by the International Agency for Research on Cancer.