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outnern +t,00ru�y, box•'I60 H F N L T H 2• �^..; Umter, SC 29150 F MMAB I L I T1 2 MERaENCY PHONE NO. 716-873-6000 ((T ys, 24hrs.) Those C T I V I T Y 0 IrORMATION PHONE NO. 803-775-6351 (M- Sam -spm ET) ra . s should be L -sed only OT EMERGENCY (800)255-3924 (24hrs) as part of ugly implemente, H.M.I.S. program. MATERIAL SAFETY DA1•A SHEET SECTION I —� DATE OF PREPARATION 6/ 2 0/ 9 1 TRADE NAME R U S T A L 0 Y ENA SAFETY GREEN MANUFACTURER CODE I.D. 86 - 2 4 8 4 4 Y- 4 4 - 1 SECTION U :HAZARDOUS .:INGREDIENTS =--- = — --- ---= – -- Z7=': - --= ALLOWABLE SARA VP INGREDIENT % BY CAS NO. EXPOSURE LEVEL 313 mm Hg WGT PPM MG/CU.M. MPPCF SKIN 20 DEG.( TITANIUM DIOXIDE 13463-67-7 TLV -TWA 10 OSHA-PEL 10 LEAD CHROMATE 5 7758-97-6 TLV -TWA 0.0500 X OSHA-PEL 0.0500 OSHA-CEIL 0.1000 MINERAL SPIRITS 64742-88-7 TLV -TWA 100 525 2 OSHA-PEL 100 525 LFL 1.0 UFL 7.0 LEAD COMPOUNDS < 1 7439-92.1 TLV -TWA 0.1500 X OSHA-PEL 0.0500 LFL = LOWER FLAMMABILITY LIMIT PERCENT UFL= UPPER FLAMMABILITY LIMIT PERCENT SKIN = SKIN ABSORPTION MUST BE CONSIDERED AS A ROUTE OF EXPOSURE C•CEILING= ALLOW. EXPOSURE LEVEL SHOULD NOT BE EXCEEDED FOR ANY TIME P E R 1 0 D MFR = MANUFACTURER RECOMMENDED EXPOSURE LIMIT STEL = SHORT TERM EXPOSURE LIMIT X - SARA 313 = CHEMICAL 1S SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF TITLE 111 .OF S . A . R . A . 40 CFR PART 372 -SECTIO _a.1 : HEALTH_ INFO AT1OhI EFFECTS OF SHORT TERM OVEREXPOSURE SWALLOWING Can cause gastrointestinal irritation, nausea, and vomiting. Aspiration of material into lung may cause chemical pneumonitis which can be fatal. INHALATION May cause nose or throat irritation. High concentrations may cause acute central nervous system depression characterized by headaches, dizziness, nausea and confusion. EYE May cause eye irritation. SKIN May cause d e f a t t i n 9 and irritation of the skin. EFFECTS OF REPEATED OVEREXPOSURE Repeated and prolonged overexposure to relatively insoluble chromates may cause lung cancer. Chronic overexposure to lead may result in severe damage to blood forming nervous, urinary and reproductive systems. Some common symptoms of chronic overexP9sure include toss of appetite, metallic taste in the mouth, anxiety, constipation, nausea weakness, insomnia, headache, muscle and joint pain, fine tremors, numbness, dizziness, hyperactivity and colic. Occupational exposure to lead is regulated by OSHA - 29 CFR 4910.1025. Pr existing kidney conditions may be aggravated by exposures to lead. Reports have associated prolonged and repeated occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH. Titanium dioxide IS NOT listed as apotential carcinogen by the National Toxicology Program, the International Agency for Research on Cancer, OSHA, or A.C.G.I.H. Dry titanium dioxide in a 24 -month inhalation study with rats revealed a significant increase in benign and malignant lung tumors in the group exposed to 250mg/M3 respirable Ti02 dust. At lower exposure levels, this significant effect was not observed. The normal clearance mechanisms of the lungs may have been overwhelmed at the 250m9/M3 exposure level, and this. may have contributed to the occurence of carcinogenicity. These results may not be directly relevant to the workplace where occupational exposure limits are observed. At the TLV the T i 0 manufacturer concludes that there is no significant hazard for man. Chromium and certain chromium compounds are listed as potential carcinogens by the National Toxicology Program . lead chromate has been listed as a potential animal carcinogen by the International Agency for Research 0 n Cancer.