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I <br />' GROUNDWATER TECHNOLOGY, INC. <br /> STANDARD OPERATING PROCEDURE <br /> CONCERNING WATER SAMPLING METHODOLOGY <br /> SOP 9 <br />' Before water sampling, each well shall be purged by pumping a minimum of four well volumes or <br /> until the discharge water indicates stabilization of temperature conductivity and pH If the well is <br /> evacuated before four well volumes are removed or stabilization is achieved, the sample should be <br />' taken when the water level in the well recovers to 80 percent of its initial level <br /> Retrieval of the water sample, sample handling and sample preservation shall be conducted <br /> according to Standard Operating Procedure 10 concerning "Sampling for Volatiles in Water" The <br /> sampling equipment used shall consist of a Teflon® and/or stainless steel samplers which meet U S <br /> Environmental Protection Agency (EPA) regulations Glass vials with TeflonO lids should be used to <br /> store the collected samples <br /> To ensure sample integrity, each vial shall be filled with the sampled water in such a way that the <br /> water stands above the lip of the vial The cap should then be quickly placed on the vial and <br /> tightened securely The vial should then be checked to ensure that air bubbles are not present prior <br /> to labeling of the sample Label information should include a sample identification number, lob <br /> identification, date, time, type of analysis requested, and sampler's name Chain-of-custody records <br /> shall be completed according to Standard Operating Procedure (SOP) 11 concerning chain of <br /> custody <br /> The vials should be immediately placed in high quality coolers for shipment to the laboratory The <br /> coolers should be packed with sufficient ice or freezer packs to ensure that the samples are kept <br /> below 4° Celsius (C) To minimize sample degradation the prescribed analysis shall take place <br /> within seven days of sample collection unless specially prepared acidified vials are used <br /> To minimize the potential for cross contamination between wells, all the well development and water <br /> sampling equipment which contacts the groundwater shall be cleaned between each sampling As a <br /> second precautionary measure, the wells shall be sampled in order of increasing contaminant <br /> concentrations (the least contaminated well first, the most contaminated well last) as established by <br /> previous analysis <br /> I <br /> I <br /> GROUNDWATER <br /> TECHNOLOGY, INC <br /> l <br />