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d-free 9 <br /> 191. <br /> rive Gasoline, <br /> Lea <br /> No.46-j Automo <br /> :Section 6 :Heaith;; €a�rard ::Data 4 . ..:..IthOU <br /> ......: . an IARC has <br /> Carcinofienicin': In 199 hrepo awned otvergall valuationpoossisbpec f mubstaaces withti Cn thii group adegquategh ehuman evidence).ce overall <br /> th <br /> evaluation m gasohoc,it assignedcause <br /> Summar),or Risks:Gasoline vapors a considered tion.Brief inhalations of high coactatratious scan esus a fatall pulasonarnervous yv edestemma Reported <br /> depression <br /> and mucous membrant and respuator}' <br /> m courts eye,Host, <br /> responses to�asoiioe vapor concentrations: 160 to 2770 ppm a mid ye and <br /> zs oin 0 minat x Higher aceatratioin several hours; nss art intoxicating in 4 to 10 <br /> and throat imtatiar�,and dizziness in 1 hr; PP producesurt <br /> minutes.If large areas of skin are exposed it gasoline,toxic amounts may be absorbed.Repeat y asiDiration after ingestion can cause sevens <br /> Certain individuals may develop hyPerseasiiivrty.ingestion can court CNS depression.pulmonary p <br /> pneumonitis.in adults,ingestion of 20 to 50 g gasoline may produce severe symptoms of poisoning. <br /> f <br /> Medical Conditions Aggravated by Long-Term Exposure:None repotted. ; <br /> Target Organs:Skin,eye,respiratory and central nervous systems. y , <br /> Pr[mary Ener}'Routes: inhalation,ingestion,skin contact est;C causes.* ' fl sh' drunkenness). <br /> Acute$frects:Acute inhalation produces intense nose,throat,end lung irritation;headaches;blurred vision;conjunctivitis;iationn of the fat_; <br /> mental confusion;staggering gait;slurred speech;and unconsciousness,sometimes withtnuvmtion o>`Ing <br /> vomiting,dizziness,fever,drowsiness,confusion,and cyanosis(a blue to dark purplish coloration of skin and mucous membrane b�sedlbusac� <br /> of oxygen).Aspiration causes choking,cough,shortness of breath,increased rate of respiration,as,fany de enem0on of the li err and kidneys, <br /> pneumonitis.Other symptoms following acute exposure include acute hemorrhage of the pancreas,Tarry deg <br /> and passive congestion Of spleen. <br /> tal <br /> Chronic Effects: Chronic inhalation results is a petite loss.nausea weight loss,insomnia,and unusual sensitivity(hyperesthcsta)of the dig <br /> extremities followed o motor weakness,muscular degeneration,and diminished tendon reflexes and coordination.Repeated skin exposure can <br /> cause blistering,drying,and lesions. <br /> FIRS AID <br /> Eves:Gently lift the eyelids and flush immediately and continuously with amounts of water until transported to an emergency medical <br /> h fl <br /> facility.Consult a physician immediately. <br /> Skin:Quick! remove conOrninated clothing Rinse with flooding amouou of water for at least 15 min.For reddened or blistered skin Consult a <br /> physician.Wash affected arta with soap end water. _ 1 <br /> Inhalation:Remove exposed person to fresh air and support breathingg as needed. <br /> Ingestion:Never give anything by mouth to an unconscious or convuising person.if in ested,do not induce vomiting due to aspiration hazard. <br /> Give conscious victim a mixture of 2 tablespoons of activated charcoal mixed in 8 oz of water to drink.Consult a physician immediately. <br /> After first aid,get appropriate in plant,paramedic,or community medical support. <br /> 77-777 <br /> Section 7 S iT .eak,axed U;spfsa Prt�cnir _... .... <br /> . .. .. <br /> Spill Nouly saftty personnel evacuate all unnecessary Personnel,remove heat and igniti°nom ureas d P�v�'c�msmimlusmpiexplosionsand or <br /> ventilation.Cleanup personotl should protect against vapor mhaTUOn and liquid contact. se nonsparking 8 regulations(29pCFR 1910.120), <br /> other noncombustible adsorbent.Dike storage areas to contra!leaks and spills.Follow applicable OSHA <br /> Aquatic Taxicir}':Bluegill,freshwater,LCs,8 ppm196 hr. <br /> Disposal:Contact your supplier or a licensed contractor for detailed recommendations.Follow applicable Federal,state,and local regulations. <br /> EPA Designations <br /> RCRA Hazardous Waste(40 CFR 261.21):Characteristic of ignitability i <br /> CERCLA Hazardous Substance(40 CFR 302.4 :Notlistrd <br /> SARA Extremei'o Hazardous Substance(40 C 355):Not listed . <br /> SARA Toxic Chemical(40 CFR 372.65):Not listed <br /> OSHA Des1gnR1ians 000 Tablc2rl-A) <br /> 29 CFR 1910.1 <br /> Luted as an Au Contaminant( . <br /> ectltteciraotedcl`n fat <br /> >. <br /> .Goggles;Wear protective eyeglasses or chemical safety goggles,per OSTIA eye-and face <br /> -protection regulations(29 CFR 1910.133).Sine), <br /> contact lens-use inppindustr)'is controversial,establish your own policy. <br /> and,if <br /> Respirator:wear a NIOSH-approved nal advice <br /> respirator T re are njr o specific NIOSH ction and use. recommends ow OSHA ons.However,fo rvapor concentrations not iisstmedi- <br /> necessary, arc respirator ui ed with organic vapor cartridge s),or arsupplied-air respirator. <br /> For <br /> do tier <br /> ately dangerous to life or health,use chemical cartridge razor a opstonge tanks),wear an SCBA.warrung. AL-parifying resp <br /> emergency or acnroutinc operations(cleaning spills, <br /> protect workers in oxygen-deficient atmospheres. , <br /> rene Or <br /> Otb vine]ear impervious <br /> s gloves,bVgood trsisiaact far protectivand FauntleLs to e clothinrevent g. Resat nc of speciCc materials can vary,as <br /> from psuch as roducts to , <br /> P y <br /> induct. t1°'� <br /> Ventilation: exhaust vtntilauon is prof parted since it icon titaminant d dispersion into the ok area y controlling ufons lat i�source ow the A PEI s <br /> (Sec.2).Local e work_ eyewashty <br /> ContaStations:Make available inminated Equipment:Remove this material from your srm5 and equipment.funder contaminated cshowerslothing beand forge wearing• <br /> Comments:Never lay drink.,or smoke in work areas•Practice good personal hygiene after using this material,especially before eating,drinking, <br /> smoking,using the toilet,or applying cosmetics. , <br /> St tlou.9;<>apec�ai Precautions:and .d a <br /> Storage Requirements;Storc in closed containers m a cool,dry well ventilated area awn}from heat and ig SHA Classsources and strong axd a or. <br /> r. <br /> agents.Protect cOuLainers from physical damage.Avoid direct sunlight Storage must meet tequiremenLs OMSHA Class IB liquid.Outside or, <br /> detached storage preferred. protection prograin that includes regular training, <br /> Engineering Controls:Avoid vapor inhalation and skin or eve contact.Consider a respiratory P P roOnly use <br /> Wear <br /> maintenance,inspection,and evaluation.Indoor use of this material requires explosion-proof c onalth hygiene and housekeeping procedures.cedu use <br /> gasoline as a fuel source due to its volatility and ilammableJexplosive nature.Practice good p YS <br /> clean work elorhing daily. <br /> Transportation Data(49 CFR 172-101,.102)_ �O shipping Narne:Gasoline <br /> g head and nature!) :1 1T10 Hazard Class:3.1 <br /> DOT Shipping Name:Gasoline(intludin casing- , <br /> DOT Hazardbass:Flammable liquid ID No.:UN 1203 <br /> ID No.: UN1203 IMO Label: Flammable liquid. t <br /> DOT Label: Flammable liquid 1MDG Packaging Group: 11 <br /> DOT Packaging Exceptions: 173.115 <br /> DOT Packaging Requirements. 173.119 <br /> 11SD5 Call a-References:26,73.89,1IXl, <br /> 101,103,124,125,127,13?,133,136.13&.140,143,lab,153,159 tied b IR Stwri,MS 9s <br /> PreparedAllison.BS;lndastrlal Hygiene Review:P)Wilson,CiH;lVtedlcal RevVea:W Silverman NID,b�suiuSCFry nriolo�w�am beiete for ux pwcrr►eY�9��P°K' <br /> non Aey oo�eesiai vee ar ap�oA.asm+lanas 4c p„b�iaEda ya�ssmv y, Eacd Jso�m <br /> eer.T;stb O 1941 M Gm�Poelia�sx�a earn ec+ma.ae.,us.aaea,m.tn m fePaCW�fod,.W aaa�n <br /> �r oreev�^0r mr pr�.+C,feq��am_Alines W��.wwwM1w{�a,eecc�N mr r�+r�».?� uamace pa•�+o�c��K+me+R��or u.Cu+� -• +.- •• - <br />