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No.470 Diesel Fuel Oil No.24D '11190
<br /> Section 6. Health Hant-d Data
<br /> ggroup,i to diesel fuels as a occupational
<br /> pwleum AufMfins�Fas in FARC probable human carcinogen(Group 2A)xlt has evaluaud distillate(light}diesel oils as not classifiable as human
<br /> Pe
<br /> carcinogens(Group 31.
<br /> Summary of Risks:Although diesel fuel's toxicologic effects should resemble kerosine's,they are somewhat more pronounced due to additives
<br /> lsuch as si3ifurized esters.oss of coordination,depending on concentration and exposure time.When reve inhalation of aerosol or mist can cause moved from exposure arca,affected persons usually recover and
<br /> r vomiting
<br /> completel),.if vomiting occurs after ingestion and if oil is aspirated into the lungs,hemorrhaging and pulmonary edema,progressing to renaRho
<br /> l in-
<br /> volvement
<br /> n-
<br /> voluli end crit CNS depression for xmcattyementt Seco dary effectsarative tio of may include hl to ypoxia(insuffletintl icient oxses ygen i be I pbody cellls)Amf infection,pneumato-
<br /> res
<br /> cele formation,and chronic lung dysfunction.Inhalation may result in euphoria cardiac dysrhythmias,rrsQiatory arrest~and CNS toxicity.
<br /> Prolonged or repeated skin contact may irritate hair follicles and block sebaceous glands,producing a rash of acne pimples and spots,usually on
<br /> arms and legs. `
<br /> Medica!Conditions Aggravated by Long Term Exposure: None reported.
<br /> Target Organs:Central nervous s}'stetn,skin,and mucous membranes. ,
<br /> Primary Entre Routes: Inhalation,ingestion.
<br /> Acute Frffects:Systemic effects from ingestion include gastrointestinal irritation,vomiting,diarrhea,and in severe cases central nervous system
<br /> depression,progressing to coma or death.Inhalation of nemsols or mists may result in increased rate of respiration,tachycardia{excessively rapid
<br /> heart beat),and cyanosis(dark purplish discoloration of the skin and mucous membranes caused by deficient blood oxygenation).
<br /> Chronic.Effects:Repeated contact with the skin causes dermatitis.
<br /> FIRST ALD transported iatciy and continuously with flooding amounts of water unfit sported to an emerge
<br /> Eyes:Gently lift the eyelids and flush immedncy medical
<br /> facilit}•.Consult a physician immediately.
<br /> Skin:Quick! remove contaminated clothing Rinse with flooding amounts of water far at least 15 min.if large areas of the body have been
<br /> exposed or ifirritationpersists,get medical help immediately'.W ash affected arra with soap and water.
<br /> Inhalation:Remove,exposed person to fresh air and support breathing as needed.
<br /> Ingestion: Never give anything by mouth to an unconscious or convulsing person.If ingested,do not induce vomiting due to aspiration hazard.
<br /> Contact a physician immcdiately.Position to avoid aspiration.
<br /> After first aid,get appropriate in-plant,paramedic,or community medical support
<br /> ?Cote to Physicians:�astnc lavage is contraindicated due IC:aspiration hazard.Preferred antidotes Circ charcoal and milk.In cases of severe
<br /> aspiration pneumonitis,consider monitoring arsenal blood gases w ensure adequate ventilation.Observe the patient for 6 hr.If vital signs become
<br /> abnormal or symptoms develop,obtain a chest x-ray.
<br /> Section? "Sp1lI,Leak;>and:DispoSal Procedures. maximumes and provide
<br /> SpilllLeak:Notify safety personnel,evacuate arca Sot aargr spills,tion and remove a u d contact.heat and nCleansup spills promptly to reducce fin plva�lpoor hazards.
<br /> ventilation.Cleanup personnel should pmtecpag p Po large ills,dike far ahead to contain.Pickup liquid forreclama-
<br /> Use a noncombustible absorbent material to ick u small spills or residues.For orspills,
<br /> tion or disposal.Da iia[release to sewers or waterways due to health and fire andlor explosion hazard.Follow applicable OSHA regulations(29
<br /> 0.120).Diesel fuel oil No.2-D spills may be environmental hazards.Report large spills'
<br /> for detailed recommendations.Follow applicable Federal,state,and local regulati
<br /> Disposal:Contact your supplier or a licensed contractorons
<br /> CFR 191 . r
<br /> EPA Designations + 1
<br /> RCRA Hazardous Waste(40 CFR 261.21):ignitable waste
<br /> CERCLA Hazardous Substance(40 CFR 302.4):Not listed
<br /> SARA 1--Klremciv SARA Toxic Chcmical Hazardous0 CFR 372.65): Not40 Fli listed
<br /> Not listed
<br /> 3
<br /> OSHA Designations
<br /> Air Contaminant(29 CFR 1910.1000,Subpart Z):Not listed
<br /> Im
<br /> iori.�8 Special.>P.rotectior :Data ::.:.:.... . .. n cc
<br /> es:Wear protective eyeglasses or chemical safety goggles,per OSHA eve-and face-protection regulations(29 CFR 1910.133).
<br /> rat a .See H-appro darespiratarwith a hor to rmistfilter and orgaespirator selectionn vapor cd use. oaitridgcftow SFor emHA ergency o onroutulations ine ope ationss(lean ng spills,
<br /> respir or
<br /> r vessels,or storage tanks),wear an SCBA.W 1unt1 prevcin�sl n c nat s tac'do not protect workers in a�ygen-defTient at^'°sP res'
<br /> :Wear impervious gloves.boots,aprons,and g tion
<br /> lation:�vidc haustav and 10C.0 ntilati a is pttfeorred since i prevents contaminant a�sparsioonn eC t`he workare b}cone 8W atlits souerread
<br /> ce t.
<br /> y Stations:Niake available in the work area emergency eyewash stations,nses ilquicks rb,a showers,and washing facilities.
<br /> minated Equipment:Never wear contact lenses in the work area:
<br /> sail Tenses may absorb,and ail lenses concentrate,irritants•Rcmovc this
<br /> al from vour shoes and equipment-Launder contaminated clothing before wearing.
<br /> ments:Here cat drink,or smoke in work areas.Practice good personal hygiene after using
<br /> this material,especially before eating,drinking.
<br /> ing,using thr toilet,or applying eosmeucs.
<br /> ion 9. Special.Precautions and Comments
<br /> 5torare Requirements: Use and storage eondiuons should be suitable for a OSHA Class i combustible Gquid Stare in closed containers m a
<br /> wcU-vcntilated to aou2N,from heat and ad'Tornand bond aU containers and cquition sources npmcp�used oxidizingn shipuig receiving,rotect r transferring operations.nsical s.Usagnonsparrk ng tools
<br /> ic
<br /> sparks,cicctr g
<br /> slid explosion enol e1ecL-ical egwpmcnt.No smoking in storage or use arras. Wear protective rubber gloves and chemical safety glasses
<br /> Enbineering�ontrols:Avoid vapor or mist inhalation and prolonged skin contact P. be tilted depending on working
<br /> when contact vdtti liquid or high mist concentration hear includes s rzgularatauning�maintenance.PrOtect3voinspec�n and required
<br /> Pacuce good
<br /> conditions.Institute a rt protection program of work clothes is r=M
<br /> personal hygiene >md housekeeping procedures.Do not wear oil contaminated clothing.At]cast wally laundering t- {
<br /> mended.Do not nut oily rags in pockets.When working with this material,Wear gloves or use barrier cream.
<br /> Transportation Uata(49 CFR 172.101) -
<br /> DOT.Shipping Name:Fuel oil
<br /> DOT Hazard Class:Combustible liquid
<br /> ID No.: NA199-1
<br /> DOT Label: Norte
<br /> DOT Packaging Exceptions: 173.178a 1
<br /> DOT Packaging Requirements:NODI 9i
<br /> AlSD .136,143 146
<br /> S COt111611-F:derentes: 1,6,7,12.73,64,101,103.126,%2k�a3 CIEi3Medtcal Rev tom:AC Aasiingiai:,MD:Edited by:IR Stuan.MS
<br /> Prepared by:Wj,Vlison,BS:industrial H79lene Revleµ:DlpptetubrrdhERr�tawtOmewir.EflurofmlOrm.++eebe"Wthcpmclsidt�'
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