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v <br /> 1 <br /> A S S O C I A T E S I N C <br /> extraction/air sparge system at the site is not warranted However, Mr Knoll also indicated that <br /> either long term monitoring or another alternative would be required prior to the site being <br /> considered for closure The workplan for performing a groundwater extraction pump test at the <br /> site was submitted on March 1, 2001 Mr Knoll approved this workplan on March 9, 2001 <br /> SAMPLING ACTIVITIES <br /> On April 3, 2002, ATC Associates personnel collected groundwater samples from monitoring <br /> wells MW2, MW3, MW4, MW5, and MW6 The locations of the monitoring wells are shown <br /> on Figure 2 Prior to collection of groundwater samples in the monitoring wells the depth to <br /> water, pH, electrical conductivity, and temperature were measured and recorded A minimum of <br /> three well casing volumes was purged from each well prior to sampling The wells were allowed <br /> to recover and samples were collected from each well using disposable bailers A similar sample <br /> was also collected from the Thornton Municipal Supply Well No 2 <br /> The groundwater samples collected from each well were submitted to State-certified Argon <br /> Laboratories (ELAP Cert No 2359) for chemical analysis of total petroleum hydrocarbons as <br /> gasoline (TPHg) utilizing EPA method 8015 modified, benzene, toluene, ethyl benzene, xylenes <br /> (BTEX), and methyl tertiary butyl ether (MTBE) utilizing EPA method 8020 MTBE was <br /> initially detected in well MW4 so this sample was also analyzed for fuel oxygenates utilizing <br /> EPA method 8260 Groundwater monitoring well purge and sample logs are contained in <br /> Attachment 1 <br /> ANALYTICAL RESULTS <br /> Laboratory analyses detected TPHg at monitoring well MW4 at a concentration of 5,700 µg/L, <br /> benzene at a concentration of 6 5 pg/L, toluene at a concentration of 6 7 gg/L, ethyl benzene at a <br /> concentration of 93 pg/L, and xylenes at a concentration of 49 pg/L MTBE was analyzed and <br /> initially detected by EPA method 8020 at a concentration of 25 µg/L in monitoring well MW4, <br /> but confirmation of the sample by EPA method 8260 determined MTBE to be below the <br /> laboratory reporting limit of 2 0 pg/L Benzene, ethyl benzene, toluene, xylenes, MTBE, and <br /> TPHg were not detected above the laboratory reporting limit at monitoring wells MW2, MW3, <br /> MW5, MW6, and the Municipal Supply Well The California Primary Maximum Contaminant <br /> Level (MCL) for benzene of 1 pg/L was exceeded at monitoring well MW4 Laboratory data <br /> sheets and chain-of-custody documentation are contained in Attachment 2 <br /> GROUNDWATER FLOW DIRECTION <br /> Water level measurements were collected from monitoring wells MW1, MW2, MW3, MW4, <br /> MW5, and MW6 on April 3, 2002 Depth to water measurements ranged from 9 11 feet to 14 05 <br /> feet below top of casing representing an increase in the water table elevation of approximately <br /> 0 68 feet since January 2002 The water level elevations were used to develop the groundwater <br /> contour map (Figure 2) Assuming that horizontal isotropic conditions prevail, the groundwater <br /> in the uppermost aquifer beneath the site generally flows in a southwesterly direction at an <br /> W 1Wordpro1625821Quarl1y12QR-2602 doc 4 <br />