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<br /> No.31b
<br /> Material Safety Cata Siticet AAM=
<br /> }3ENZENE
<br /> From Gcnium's Reference Collection Up (Revision D)
<br /> Genium Publishing Cotporatsoi Issued: November.1978
<br /> 1145 Catal}•n stint I r(��
<br /> Schenectady,NY 1�L303.1836 USA Gk H}nu PVaLISHtHG CaRp. `et kscd• April I J
<br /> 25
<br /> (518)377-EF15
<br /> SCC'I'ION 1. MATERIAL IDENT1lr1CATIU?� 3
<br /> Z a
<br /> Tiaterlai dame: BFN7rNF linolcom,airplane dopcs,
<br /> Description (Origln/Uses): Used in the manufacture and tdi inal ch.rucals d• HI�15
<br /> varnishes,and lacquers;and as a solvent for waxes,resins, H 2
<br /> F 3 R 1
<br /> Other Deslgnadons: llcnzol; Phene,Phcny'ihydride C,?I�;1�1GSkiRTECSt�o•C1'1:461}x0; R 3 1 4
<br /> CAS No,0071-43-2PPG` S 2
<br /> ItJanurarturer: Contact tour supplier or distributor. Consult the latest ediuon of Ltc Gncr icalwcct ,Sce sect.S K 4
<br /> Buyers'Guide(Genium ref.73)for a list of suppliers. r� I O S UR E LI It I IT S
<br /> SECTION 3. INGREDIENTS Ca 1IA7.ARI!S I Ca 100 OSHA PEI.
<br /> Sen?. S-HrIVA:1 ppmenc,CAS No.06713 2 15-hiin Ceiling:5 ppm
<br /> Acuan Lcvcl: 0.5 ppm
<br /> ACGJH TLV,1987-88
<br /> TLV-TWA: to ppm,30 mg/rO
<br /> Toxicity Data* .
<br /> Human,lnhalauon,LCL: 2000 ppm'S Min
<br /> Human,Qral,TDL: 130?M9/k9
<br /> `See NOSH,RT1 C5,tat addition at data with rclercnc:s to iritaiive,me=Sentc i.4uman,Inhalation,TCL: 210 PPM
<br /> lumorigcnic,and reproductive effects'
<br /> _ SECTION 3: PI-IYSICAL DATA 15ater Sotebi Volume:
<br /> )� Slight
<br /> Bolling Paint: l76'F(60'C) Sc Vofatlle by'Volume: ra
<br /> Molecular Wel„ht: too
<br /> 75 Gramslhioic
<br /> �T AleltinpPoint: 42'F(5.5 at68'F(20'C) 1 0.57865 at 66'F(20'C)
<br /> Vapor Pressure: 75Torrs Specific Gravity (H,o = )
<br /> Vapor Density(Air 1): >1
<br /> Appearance and Odor: A colorless liquid;characteristic aromatic oder.
<br /> SECTION 4. FIRE AND EXPLOSION DATA'
<br /> LC)tiir R PP R
<br /> Autoignition Temperature Flammability Limit in Air
<br /> Flash Paint and Method ,,by Volume
<br /> 12'F(1 y.l'C)CC 928'F(496'C) «rater may be ineffective as an extinguishing
<br /> Eytlneuishinp\iedia: Use dry cltcm-,cal,foam,or carbon dioxide Ln put out bcazcne fares. y
<br /> agent
<br /> Extinguishing
<br /> it can scaucr and spread the fire.Use water to cool RM-cxpaSed cantamen,flush spiiis away fmm exposures,disperse benzene
<br /> vapor,
<br /> and prated personnel attempting to Stop an unignited benzene teat' eft>rx ]osive and llanatnable
<br /> Unusual Fire ar Explosion 1Jazardsr Benzene vapor is heavier than air and earl colic t in low-lying arms such as sumps ol2z
<br /> Eliminate all sources of ignition there to prevent ad angerous flashback to the osi;:nal liquid benzenVial e.D angimizes er- P
<br /> benzrne vapor-air m'ixtures can easily form at room icmperetarc;always use this material to u Lh a full farce,i ce opera>zd in the p'•cssurc into
<br /> general work areas• apparatus(SCBA)
<br /> Special Fire-right!ng Procedures; Wt2r a self-containcd brcathing pp
<br /> demand o:pasiuvc-pressure mcdc.
<br /> SECTION REACTT�'ITY I)AT.A
<br /> Benzene is stable in closed containers during routine of crations. It does not cndcrg°Naz rdous Po]ymerizaUon.
<br /> ortEd in
<br /> um
<br /> oxy cn,ozone,perchloratcs,
<br /> Chemical lneompaiibikities:Haz�dous chemical reactions involvin^;bsrrne and the following materialsper
<br /> hlorurc�d sodium Pero ide.
<br /> refercncc 6::bromine pcataflueridc,chior, chla iac t:iftuoridc,chror,.:c z tot Ssc�sum ly roxideyl hsilvcr p g
<br /> nerchlory4 nuoride.nd alu.:irsm chloride,permangan=res and sulfuric acid,p P=
<br /> Conditions to,,vaid: Avoid all exposure 10 saures of ignition and t°incompatible ehe:. eaks.
<br /> 9=5 •c ca boar�noxtd
<br /> . .. be produced during benzene fires.
<br /> -----
<br /> Hazardous Products of Decompostlron: Toarc7is ^ m')__--
<br /> ce;y:�onlaasscr^,�mr:�,.n:nzc�.�,l,a. t..
<br />
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