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<br /> No.385 ETli1L BEENZEN-E, MSS
<br /> SECTION 6. HEALTH HAZARD INFORMATION. corp.
<br /> flush eyes,including under the eyelids,gently but thoroughly with flooding Am"=of running water for at last 15 1:zutes.Skin.Rinsc
<br /> the affected arca with plenty of water,then wash it with soAp and water..Inhalation.Remove the exposed person to fresh air;restore andlor
<br /> support his or her breathing as needed..Have q':alifice,medical personocl adrtinis::r oxygen As rceuircd.Ingestion.Unlikely.Should
<br /> Ll:is type of ex}csurc occur,the upiration hazard must be considered.Do not inducz vomiting unlc:s directed to do so by a phys',cian.To
<br /> prevent aspiration by spontaneous vomiting,Ycep the r:Ctira's hca-1 low(bctw'eea his or het knees).Get medical help(in plant,para-
<br /> medic,community)for all exposures.Sect'prompt medical assistance for fumhcr Lmatmcay observation,and support after first aid,Note
<br /> to Physician: profcssion:J judgment is n:quirtd as to A,hc1hcT Or no:to induce vomiting because of the possibility of aspiration.A gastric
<br /> lavage map beadministcrcd,followed by saline catharsis,ii chis procedure is appy priatc to the specific incident.Moditor cardiac and
<br /> pulmonary functions.
<br /> SECTIOi\' 7.- SPILL, LEAK. AND DISPOSAL -TROCEI)L;RES
<br /> SpIlVlxak: 1`ptify safety'pezonnel,cVdrUaLe unoccesaary'personnel,ciLmiozic a_ll sources of ignition immediately,and provide adcquaL-
<br /> explosion-proof ventilation.Cleanup personocl need p.mr--tion against slain or eye contact with this liquid as wall as inhalation of its vapor
<br /> (see sect_6).Contain Im-ge spills and collect waste or ab rib it with an finer,ma'=z1 such 25 stayed,earth,or vermiculite.Usc nonsparEng
<br /> tools w place w'astc liquid er absorbent into closable containers for disposal.Kccp waste out of sewers,watersheds,and waterway's.1i'.ste
<br /> Disposal: Contact your supplier or a licensed contractor for dc:ailcd rccomrncndzdcns.FoIlou Federal,sta„and 10-LI regulations.
<br /> DSHA Designations
<br /> Listed as an Air Coruminant(29 CFR 1550.10?7 Subpart Z).
<br /> EPA Df-d.-nations(40 CFA 302.5) -
<br /> C'cRCLA 112111dous Substanec,Reponzble Quaa6ly:IDYJ lbs(454 kg),per the Clan Water Act(CWA),E¢311(b)(5)and 301(a).
<br /> SECTION S. SPECIAL P0-T-✓CTIO*i INFORMATION
<br /> Goggles: ;]ways wear prat ctive evcglasscs or chemical safety goggles. Where splashing is possible,w'car a full face shield.Follow
<br /> OSHA eye-and face-protection regulations(29 CFR 1910.133).Respirator: wcz a NIOSH-zppr oved respi aror per Geuium reference 96
<br /> far the naximu a•usc concentrations an:Uor the exposure limits cited in section 2.Follow OSHA resni;alar regulations(29 CFR 1910.154).
<br /> For emergency or noarcudne operations(spills or cleaning rca--tor vessels and sto ace tznls),wear an SCSA.Warning: Air-purifying
<br /> respirators will not protect w'orkem in oxygen-defieicat atmo.phcros.Other. A'ear impervious gloves,boots,aprons,And gaunticu,etc.,to
<br /> prevent prolonged or repeated skin eonwct with this maLnal.Ventilation' install and operate general and local m2ximum,explosion-proof
<br /> venLilation sysirms powerful enough to t tainmia airborne levels of this mztcrial b.-low the OSHA PEL standard cited in section 2.Local
<br /> exhaust ventilation is preferred because it prti cuts dispersion of the contaminant into the general wort sea by elitninzting is at its source.
<br /> Consult the latest edition of Genium reference 103 for detailed recommendations.Safety Stations: h4akc emergency eyewash stations,
<br /> s21etylquick-drench showers,and washing facilities zvzilzble in u'nr):ants.Contaminated Equipment: Contact lenses pose a special
<br /> hazard;soft lenses may absorb irntzns,and all lenses concentrzte them.Do no:w'car contact leases in any work area,Remove eontzmi-
<br /> sated clothing and launder it before wearing it again,clan this material from shoes and equipment Comments: Practice good personal
<br /> hygiene;always wash thoroughly after Usi-it this material and before eating•drinking,smoL'ng.Using the toilet,o:applying cosmetics.
<br /> Keep it off your clothing and equipment.Avoid Ir ansfemng it from your hands m you:MCI-11h while citing,dri^l ting,W$ 0''ting.Do no.,
<br /> eat,drtolt,or smoke in any wort:=2z Do pot inhale ethyl bcnzenc vapor.
<br /> SECTION 9.+.SPECIAL PRECAUTIONS AND COMIMIENTS
<br /> Storagc/Segregation: Sore ethyl benzene in closed containers in a cool,dry,wcL-v'cntilated=A away from sources of ignition and
<br /> strong oxidizers.Protect containers from physical damage.Special 112ndlinglStorage: Outride,isolated,detached,orremnte storage is
<br /> rccom.mcndcd for large quantities of ethyl benzene.]sola~bull:storage areas from acute fire hazards.EnIneering Controls: Matic sure
<br /> 211 engincel4ng systems(production,=n'sportatioo)are of maximum explosion-P, of design.To pit vent static sparks,electrically ground
<br /> And bondall coeizi c ,pie__lia_s,gree,used in shipping,transferring,reacting,production,and sampling operations.Other: Use-safety
<br /> cans for eansferrirg small zrnou7u of ethyl benzene.
<br /> Transportation Data(49 CrR 172.101-2)
<br /> DOT Shippin.-Namc. ELhy'l Bcu=ne
<br /> DOT Hazard C125S: Fla_!able liquid
<br /> ID No.UN 1175
<br /> DOT Label: Flammable Liquid
<br /> DOT Packaging Exceptions: 49 CFR i 72.115
<br /> DOT Packaging Requirements: 49 CFF 173.119
<br /> 1.150 Shipping Same. Et`:ylbc,;xcnc
<br /> 1.110 Hazard Class: 3.:
<br /> IMO Label: Fi=i:ble Liquid
<br /> IMIDG Pacl:2gin;.Group: 11
<br /> References: 1,96,3S,6-.94,NO,116.117,M.I=
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